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Selective Photooxidation of a Mustard‐Gas Simulant Catalyzed by a Porphyrinic Metal–Organic Framework
Abstract
The photooxidation of a mustard‐gas simulant, 2‐chloroethyl ethyl sulfide (CEES), is studied using a porphyrin‐based metal–organic framework (MOF) catalyst. At room temperature and neutral pH value, singlet oxygen is generated by PCN‐222/MOF‐545 using an inexpensive and commercially available light‐emitting diode. The singlet oxygen produced by PCN‐222/MOF‐545 selectively oxidizes CEES to the comparatively nontoxic product 2‐chloroethyl ethyl sulfoxide (CEESO) without formation of the highly toxic sulfone product. In comparison to current methods, which utilize hydrogen peroxide as an oxidizing agent, this is a more realistic, convenient, and effective method for mustard‐gas detoxification.
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Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Cited by
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Metal-organic frameworks with photocatalytic bactericidal activity for integrated air cleaning
Li, P., Li, J., Feng, X., Li, J., Hao, Y., Zhang, J., Wang, H., Yin, A., Zhou, J., Ma, X., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-10218-9 · Cited by 802
CD-MOF: A Versatile Separation Medium
Hartlieb, K. J., Holcroft, J. M., Moghadam, P. Z., Vermeulen, N. A., Algaradah, M. M., Nassar, M. S., Botros, Y. Y., Snurr, R. Q., & Stoddart, J. F. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b12860 · Cited by 323
A Base-Resistant Metalloporphyrin Metal–Organic Framework for C–H Bond Halogenation
Lv, X.-L., Wang, K., Wang, B., Su, J., Zou, X., Xie, Y., Li, J.-R., & Zhou, H.-C. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b09463 · Cited by 312
Lacombe, S., & Pigot, T. (2016) · Catalysis Science & Technology · doi:10.1039/c5cy01929j · Cited by 82
Metadata
- Authors
- Liu, Y., Howarth, A. J., Hupp, J. T., & Farha, O. K.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-06-17
- Volume
- 54
- Issue
- 31
- Pages
- 9001-9005
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2171661037
- Cited by
- 317
- References
- 1
- FWCI
- 11.86
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, Y., Howarth, A. J., Hupp, J. T., & Farha, O. K. (2015). Selective Photooxidation of a Mustard‐Gas Simulant Catalyzed by a Porphyrinic Metal–Organic Framework. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201503741
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