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Cited by 172

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Polymeric Micelle Assembly for the Smart Synthesis of Mesoporous Platinum Nanospheres with Tunable Pore Sizes

Li, Yunqi, Bastakoti, Bishnu Prasad, Malgras, Victor, Li, Cuiling, Tang, Jing, Kim, Jung Ho, Yamauchi, Yusuke·2015·Angewandte Chemie International Edition

Abstract

A facile method for the fabrication of well‐dispersed mesoporous Pt nanospheres involves the use of a polymeric micelle assembly. A core–shell–corona type triblock copolymer [poly(styrene‐b‐2‐vinylpyridine‐b‐ethylene oxide), PS‐b‐P2VP‐b‐PEO] is employed as the pore‐directing agent. Negatively charged PtCl 42− ions preferably interact with the protonated P2VP+ blocks while the free PEO chains prevent the aggregation of the Pt nanospheres. The size of the mesopores can be finely tuned by varying the length of the PS chain. Furthermore, it is demonstrated that the metallic mesoporous nanospheres thus obtained are promising candidates for applications in electrochemistry.

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Metadata

Authors
Li, Y., Bastakoti, B. P., Malgras, V., Li, C., Tang, J., Kim, J. H., & Yamauchi, Y.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2015-08-11
Volume
54
Issue
38
Pages
11073-11077
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2096065466
Cited by
172
References
3
FWCI
15.05
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Polymeric Micelle Assembly for the Smart Synthesis of Mesoporous Platinum Nanospheres with Tunable Pore Sizes. https://app.cochat.ai/papers/10.1002/anie.201505232
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Li, Y., Bastakoti, B. P., Malgras, V., Li, C., Tang, J., Kim, J. H., & Yamauchi, Y. (2015). Polymeric Micelle Assembly for the Smart Synthesis of Mesoporous Platinum Nanospheres with Tunable Pore Sizes. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201505232

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