The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Nanostructured Ni2P as a Robust Catalyst for the Hydrolytic Dehydrogenation of Ammonia–Borane
Abstract
Ammonia–borane (AB) is a promising chemical hydrogen‐storage material. However, the development of real‐time, efficient, controllable, and safe methods for hydrogen release under mild conditions is a challenge in the large‐scale use of hydrogen as a long‐term solution for future energy security. A new class of low‐cost catalytic system is presented that uses nanostructured Ni 2 P as catalyst, which exhibits excellent catalytic activity and high sustainability toward hydrolysis of ammonia–borane with the initial turnover frequency of 40.4 mol(H2) mol(Ni2P)−1 min−1 under air atmosphere and at ambient temperature. This value is higher than those reported for noble‐metal‐free catalysts, and the obtained Arrhenius activation energy (Ea=44.6 kJ mol−1) for the hydrolysis reaction is comparable to Ru‐based bimetallic catalysts. A clearly mechanistic analysis of the hydrolytic reaction of AB based on experimental results and a density functional theory calculation is presented.
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Cites
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Liu, J., Liu, Y., Liu, N., Han, Y., Zhang, X., Huang, H., Lifshitz, Y., Lee, S.-T., Zhong, J., & Kang, Z. (2015) · Science · doi:10.1126/science.aaa3145 · Cited by 4,468
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Cited by
Shi, Y., Li, M., Yu, Y., & Zhang, B. (2020) · Energy & Environmental Science · doi:10.1039/d0ee02577a · Cited by 426
Hou, C.-C., Li, Q., Wang, C.-J., Peng, C.-Y., Chen, Q.-Q., Ye, H.-F., Fu, W.-F., Che, C.-M., López, N., & Chen, Y. (2017) · Energy & Environmental Science · doi:10.1039/c7ee01553d · Cited by 267
Self-citationWei, Q., Qiu, S., Yin, C., Liu, J., Xia, Y., Wen, X., Zou, Y., Xu, F., Sun, L., & Chu, H. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.166207 · Cited by 55
Hou, C.-C., Chen, Q.-Q., Li, K., Wang, C.-J., Peng, C.-Y., Shi, R., & Chen, Y. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta00607a · Cited by 52
Self-citationYue, Z., Cheng, Y., Jiang, Q., Bai, X., Fang, X., Zhao, X., Yao, Y., Dong, D., Che, Y., & Chang, G. (2024) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.4c02523 · Cited by 6
Metadata
- Authors
- Peng, C., Kang, L., Cao, S., Chen, Y., Lin, Z., & Fu, W.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-11-06
- Volume
- 54
- Issue
- 52
- Pages
- 15725-15729
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2170212824
- Cited by
- 236
- References
- 2
- FWCI
- 10.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Peng, C., Kang, L., Cao, S., Chen, Y., Lin, Z., & Fu, W. (2015). Nanostructured Ni2P as a Robust Catalyst for the Hydrolytic Dehydrogenation of Ammonia–Borane. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201508113
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