The DOI matches its Crossref record.
Photochemical Reduction of Low Concentrations of CO2 in a Porous Coordination Polymer with a Ruthenium(II)–CO Complex
Abstract
Direct use of low pressures of CO 2 as a C1 source without concentration from gas mixtures is of great interest from an energy‐saving viewpoint. Porous heterogeneous catalysts containing both adsorption and catalytically active sites are promising candidates for such applications. Here, we report a porous coordination polymer (PCP)‐based catalyst, PCP‐Ru II composite, bearing a Ru II‐CO complex active for CO 2 reduction. The PCP‐Ru II composite showed improved CO 2 adsorption behavior at ambient temperature. In the photochemical reduction of CO 2 the PCP‐Ru II composite produced CO, HCOOH, and H 2. Catalytic activity was comparable with the corresponding homogeneous Ru II catalyst and ranks among the highest of known PCP‐based catalysts. Furthermore, catalytic activity was maintained even under a 5 % CO 2/Ar gas mixture, revealing a synergistic effect between the adsorption and catalytically active sites within the PCP‐Ru II composite.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Carbon capture and conversion using metal–organic frameworks and MOF-based materials
Ding, M., Flaig, R. W., Jiang, H.-L., & Yaghi, O. M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00829a · Cited by 2,616
Cocatalysts for Selective Photoreduction of CO2into Solar Fuels
Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,304
Metal-Organic Frameworks for Energy Applications
Wang, H., Zhu, Q.-L., Zou, R., & Xu, Q. (2017) · Chem · doi:10.1016/j.chempr.2016.12.002 · Cited by 1,200
Magnetic functionalities in MOFs: from the framework to the pore
Mínguez Espallargas, G., & Coronado, E. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00653e · Cited by 802
Pristine Metal–Organic Frameworks and their Composites for Energy Storage and Conversion
Liang, Z., Qu, C., Guo, W., Zou, R., & Xu, Q. (2018) · Advanced Materials · doi:10.1002/adma.201702891 · Cited by 787
Metadata
- Authors
- Kajiwara, T., Fujii, M., Tsujimoto, M., Kobayashi, K., Higuchi, M., Tanaka, K., & Kitagawa, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-01-22
- Volume
- 55
- Issue
- 8
- Pages
- 2697-2700
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2273008607
- Cited by
- 263
- References
- 0
- FWCI
- 8.13
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Photochemical Reduction of Low Concentrations of CO2 in a Porous Coordination Polymer with a Ruthenium(II)–CO Complex. https://app.cochat.ai/papers/10.1002/anie.201508941
- The paper
- Kajiwara, T., Fujii, M., Tsujimoto, M., Kobayashi, K., Higuchi, M., Tanaka, K., & Kitagawa, S. (2016). Photochemical Reduction of Low Concentrations of CO2 in a Porous Coordination Polymer with a Ruthenium(II)–CO Complex. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201508941
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
