The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.
Single‐Crystalline Ultrathin Nickel Nanosheets Array from In Situ Topotactic Reduction for Active and Stable Electrocatalysis
Open accessAbstract
Simultaneously synthesizing and structuring atomically thick or ultrathin 2D non-precious metal nanocrystal may offer a new class of materials to replace the state-of-art noble-metal electrocatalysts; however, the synthetic strategy is the bottleneck which should be urgently solved. Here we report the synthesis of an ultrathin nickel nanosheet array (Ni-NSA) through in situ topotactic reduction from Ni(OH)2 array precursors. The Ni nanosheets showed a single-crystalline lamellar structure with only ten atomic layers in thickness and an exposed (111) facet. Combined with a superaerophobic (low bubble adhesive) arrayed structure the Ni-NSAs exhibited a dramatic enhancement on both activity and stability towards the hydrazine-oxidation reaction (HzOR) relative to platinum. Furthermore, the partial oxidization of Ni-NSAs in ambient atmosphere resulted in effective water-splitting electrocatalysts for the hydrogen-evolution reaction (HER).
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“Among them, 2D CoP nanosheets are more feasible to enhance HER catalytic activity, since the 2D nanostructures enable to expose catalytically active sites which promote interfacial charge transfer.”
From Sub‐1.5 nm Ultrathin CoP Nanosheet Aerogel: Efficient Electrocatalyst for Hydrogen Evolution Reaction at All pH Values (2018) · cites this paper as [23]
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Cites
Electric Field Effect in Atomically Thin Carbon Films
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Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
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Experimental observation of the quantum Hall effect and Berry's phase in graphene
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Two-dimensional atomic crystals
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Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials
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Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
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Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene
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Metallic nanostructures with low dimensionality for electrochemical water splitting
Li, L., Wang, P., Shao, Q., & Huang, X. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00013b · Cited by 1,049
Guo, W., Zhang, K., Liang, Z., Zou, R., & Xü, Q. (2019) · Chemical Society Reviews · doi:10.1039/c9cs00159j · Cited by 895
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Tang, C., Zhang, R., Lu, W., Wang, Z., Liu, D., Hao, S., Du, G., Asiri, A. M., & Sun, X. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201608899 · Cited by 810
Self-citationZhou, D., Li, P., Lin, X. X., McKinley, A., Kuang, Y., Liu, W., Lin, W., Sun, X., & Duan, X. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00186h · Cited by 772
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Metadata
- Authors
- Kuang, Y., Feng, G., Li, P., Bi, Y., Li, Y., & Sun, X.
- Affiliations
- State Key Laboratory of Chemical Resource Engineering (CN)
- Corresponding author
- Sun, Xiaoming
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-11-19
- Volume
- 55
- Issue
- 2
- Pages
- 693-697
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- PMC
- PMC4706644
- OpenAlex
- W2173150847
- Cited by
- 259
- References
- 41
- Citations by year
- 2026: 4 · 2025: 15 · 2024: 13 · 2023: 19 · 2022: 20 · 2021: 39 · 2020: 32 · 2019: 30 · 2018: 32 · 2017: 35 · 2016: 20
- FWCI
- 8.59
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Angewandte Chemie International Edition (publishedVersion, other-oa)
- PubMed Central (publishedVersion, cc-by-nc)
- PubMed (publishedVersion)
- Funders
- Funded Access
- National Natural Science Foundation of China
- 973 Program (2011CBA00503, 2011CB932403)
- Program for Changjiang Scholars and Innovative Research Team in the University
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemistry › Analytical Chemistry › Electrochemical sensors and biosensors
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Keywords
- topotactic reduction, superaerophobic surfaces, hydrazine oxidation, hydrogen evolution reaction, water splitting, non-precious metal electrocatalysts, catalyst stability
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