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Synthesis, Separation, and Characterization of Small and Highly Fluorescent Nitrogen‐Doped Carbon NanoDots

Open access
Arcudi, Francesca, Đorđević, Luka, Prato, Maurizio·2016·Angewandte Chemie International Edition

Abstract

A facile bottom‐up approach to carbon nanodots (CNDs) is reported, using a microwave‐assisted procedure under controlled conditions. The as‐prepared nitrogen‐doped CNDs (NCNDs) show narrow size‐distribution, abundant surface traps and functional groups, resulting in tunable fluorescent emission and excellent solubility in water. Moreover, we present a general method for the separation of NCNDs by low‐pressure size‐exclusion chromatography, leading to an even narrower size distribution, different surface composition, and optical properties. They display among the smallest size and the highest FLQYs reported so far. 13 C‐enriched starting materials produced N 13 CNDs suitable for thorough NMR studies, which gave useful information on their molecular structure. Moreover, they can be easily functionalized and can be used as water‐soluble carriers. This work provides an avenue to size‐ and surface‐controllable and structurally defined NCNDs for applications in areas such as optoelectronics, biomedicine, and bioimaging.

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Metadata

Authors
Arcudi, F., Đorđević, L., & Prato, M.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2016-01-06
Volume
55
Issue
6
Pages
2107-2112
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2223933392
Cited by
351
References
39
FWCI
19.06
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Synthesis, Separation, and Characterization of Small and Highly Fluorescent Nitrogen‐Doped Carbon NanoDots. https://app.cochat.ai/papers/10.1002/anie.201510158
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Arcudi, F., Đorđević, L., & Prato, M. (2016). Synthesis, Separation, and Characterization of Small and Highly Fluorescent Nitrogen‐Doped Carbon NanoDots. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201510158

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