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A Two‐Dimensional Zirconium Carbide by Selective Etching of Al3C3 from Nanolaminated Zr3Al3C5

Open access
Zhou, Jie, Zha, Xianhu, Chen, Fan Y., Ye, Qun, Eklund, Per, Du, Shiyu, Huang, Qing·2016·Angewandte Chemie International Edition

Abstract

The room‐temperature synthesis of a new two‐dimensional (2D) zirconium‐containing carbide, Zr 3 C 2 T z MXene is presented. In contrast to traditional preparation of MXene, the layered ternary Zr 3 Al 3 C 5 material instead of MAX phases is used as source under hydrofluoric acid treatment. The structural, mechanical, and electronic properties of the synthesized 2D carbide are investigated, combined with first‐principles density functional calculations. A comparative study on the structrual stability of our obtained 2D Zr 3 C 2 T z and Ti 3 C 2 T z MXenes at elevated temperatures is performed. The obtained 2D Zr 3 C 2 T z exhibits relatively better ability to maintain 2D nature and strucural integrity compared to Ti‐based Mxene. The difference in structural stability under high temperature condition is explained by a theoretical investigation on binding energy.

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Metadata

Authors
Zhou, J., Zha, X., Chen, F. Y., Ye, Q., Eklund, P., Du, S., & Huang, Q.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2016-03-09
Volume
55
Issue
16
Pages
5008-5013
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2294706179
Cited by
631
References
4
FWCI
12.52
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: A Two‐Dimensional Zirconium Carbide by Selective Etching of Al3C3 from Nanolaminated Zr3Al3C5. https://app.cochat.ai/papers/10.1002/anie.201510432
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Zhou, J., Zha, X., Chen, F. Y., Ye, Q., Eklund, P., Du, S., & Huang, Q. (2016). A Two‐Dimensional Zirconium Carbide by Selective Etching of Al3C3 from Nanolaminated Zr3Al3C5. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201510432

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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