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A Two‐Dimensional Zirconium Carbide by Selective Etching of Al3C3 from Nanolaminated Zr3Al3C5
Open accessAbstract
The room‐temperature synthesis of a new two‐dimensional (2D) zirconium‐containing carbide, Zr 3 C 2 T z MXene is presented. In contrast to traditional preparation of MXene, the layered ternary Zr 3 Al 3 C 5 material instead of MAX phases is used as source under hydrofluoric acid treatment. The structural, mechanical, and electronic properties of the synthesized 2D carbide are investigated, combined with first‐principles density functional calculations. A comparative study on the structrual stability of our obtained 2D Zr 3 C 2 T z and Ti 3 C 2 T z MXenes at elevated temperatures is performed. The obtained 2D Zr 3 C 2 T z exhibits relatively better ability to maintain 2D nature and strucural integrity compared to Ti‐based Mxene. The difference in structural stability under high temperature condition is explained by a theoretical investigation on binding energy.
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Cites
Electric Field Effect in Atomically Thin Carbon Films
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., Grigorieva, I. V., & Firsov, A. A. (2004) · Science · doi:10.1126/science.1102896 · Cited by 66,834
The electronic properties of graphene
Castro Neto, A. H., Guinea, F., Peres, N. M. R., Novoselov, K. S., & Geim, A. K. (2009) · Reviews of Modern Physics · doi:10.1103/revmodphys.81.109 · Cited by 24,803
Superior Thermal Conductivity of Single-Layer Graphene
Balandin, A. A., Ghosh, S., Bao, W., Calizo, I., Teweldebrhan, D., Miao, F., & Lau, C. N. (2008) · Nano Letters · doi:10.1021/nl0731872 · Cited by 13,823
Synthesis and thermal stability of two-dimensional carbide MXene Ti3C2
Li, Z., Wang, L., Sun, D., Zhang, Y., Liu, B., Hu, Q., & Zhou, A. (2015) · Materials Science and Engineering: B · doi:10.1016/j.mseb.2014.10.009 · Cited by 928
Cited by
Ten Years of Progress in the Synthesis and Development of MXenes
Naguib, M., Barsoum, M. W., & Gogotsi, Y. (2021) · Advanced Materials · doi:10.1002/adma.202103393 · Cited by 1,257
Jiang, X., Kuklin, A. V., Baev, A., Ge, Y., Ågren, H., Zhang, H., & Prasad, P. N. (2020) · Physics Reports · doi:10.1016/j.physrep.2019.12.006 · Cited by 914
Electrochemical etching of Ti2AlC to Ti2CTx (MXene) in low-concentration hydrochloric acid solution
Sun, W., Shah, S. A., Chen, Y., Tan, Z., Gao, H., Habib, T., Radovic, M., & Green, M. J. (2017) · J. Mater. Chem. A · doi:10.1039/c7ta05574a · Cited by 854
Recent advance in MXenes: A promising 2D material for catalysis, sensor and chemical adsorption
Zhu, J., Ha, E., Zhao, G., Zhou, Y., Huang, D., Yue, G., Hu, L., Sun, N., Wang, Y., Lee, L. Y. S., et al. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.09.012 · Cited by 659
Recent Advances in Oxidation Stable Chemistry of 2D MXenes
Cao, F., Zhang, Y., Wang, H., Khan, K., Tareen, A. K., Qian, W., Zhang, H., & Ågren, H. (2022) · Advanced Materials · doi:10.1002/adma.202107554 · Cited by 648
Metadata
- Authors
- Zhou, J., Zha, X., Chen, F. Y., Ye, Q., Eklund, P., Du, S., & Huang, Q.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-03-09
- Volume
- 55
- Issue
- 16
- Pages
- 5008-5013
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2294706179
- Cited by
- 631
- References
- 4
- FWCI
- 12.52
- Type
- journal article
- Language
- en
- Open access
- green
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- Zhou, J., Zha, X., Chen, F. Y., Ye, Q., Eklund, P., Du, S., & Huang, Q. (2016). A Two‐Dimensional Zirconium Carbide by Selective Etching of Al3C3 from Nanolaminated Zr3Al3C5. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201510432
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