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Organolead Halide Perovskite Nanocrystals: Branched Capping Ligands Control Crystal Size and Stability

Luo, Binbin, Pu, Ying‐Chih, Lindley, Sarah A., Yang, Yi, Lu, Liqiang, Li, Yat, Li, Xueming, Zhang, Jin Z.·2016·Angewandte Chemie International Edition

Abstract

CH 3 NH 3 PbBr 3 perovskite nanocrystals (PNCs) of different sizes (ca. 2.5–100 nm) with high photoluminescence (PL) quantum yield (QY; ca. 15–55 %) and product yield have been synthesized using the branched molecules, APTES and NH 2‐POSS, as capping ligands. These ligands are sterically hindered, resulting in a uniform size of PNCs. The different capping effects resulting from branched versus straight‐chain capping ligands were compared and a possible mechanism proposed to explain the dissolution–precipitation process, which affects the growth and aggregation of PNCs, and thereby their overall stability. Unlike conventional PNCs capped with straight‐chain ligands, APTES‐capped PNCs show high stability in protic solvents as a result of the strong steric hindrance and propensity for hydrolysis of APTES, which prevent such molecules from reaching and reacting with the core of PNCs.

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Metadata

Authors
Luo, B., Pu, Y., Lindley, S. A., Yang, Y., Lu, L., Li, Y., Li, X., & Zhang, J. Z.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2016-06-13
Volume
55
Issue
31
Pages
8864-8868
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2431896681
Cited by
334
References
29
FWCI
20.89
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Organolead Halide Perovskite Nanocrystals: Branched Capping Ligands Control Crystal Size and Stability. https://app.cochat.ai/papers/10.1002/anie.201602236
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Luo, B., Pu, Y., Lindley, S. A., Yang, Y., Lu, L., Li, Y., Li, X., & Zhang, J. Z. (2016). Organolead Halide Perovskite Nanocrystals: Branched Capping Ligands Control Crystal Size and Stability. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201602236

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