The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Pt3Co Octapods as Superior Catalysts of CO2 Hydrogenation
Abstract
As the electron transfer to CO 2 is a critical step in the activation of CO 2, it is of significant importance to engineer the electronic properties of CO 2 hydrogenation catalysts to enhance their activity. Herein, we prepared Pt 3 Co nanocrystals with improved catalytic performance towards CO 2 hydrogenation to methanol. Pt 3 Co octapods, Pt 3 Co nanocubes, Pt octapods, and Pt nanocubes were tested, and the Pt 3 Co octapods achieved the best catalytic activity. Both the presence of multiple sharp tips and charge transfer between Pt and Co enabled the accumulation of negative charges on the Pt atoms in the vertices of the Pt 3 Co octapods. Moreover, infrared reflection absorption spectroscopy confirmed that the high negative charge density at the Pt atoms in the vertices of the Pt 3 Co octapods promotes the activation of CO 2 and accordingly enhances the catalytic activity.
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Cites
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Self-citationKim, D., Resasco, J., Yu, Y., Asiri, A. M., & Yang, P. (2014) · Nature Communications · doi:10.1038/ncomms5948 · Cited by 1,374
He, Z., Qian, Q., Ma, J., Meng, Q., Zhou, H., Song, J., Liu, Z., & Han, B. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507585 · Cited by 313
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Cited by
Significant Advances in C1 Catalysis: Highly Efficient Catalysts and Catalytic Reactions
Bao, J., Yang, G., Yoneyama, Y., & Tsubaki, N. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b03924 · Cited by 367
Liu, Y., Xiao, C., Huang, P., Cheng, M., & Xie, Y. (2018) · Chem · doi:10.1016/j.chempr.2018.02.006 · Cited by 282
Hou, L., Li, Z., Jang, H., Kim, M. G., Cho, J., Liu, S., & Liu, X. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202315633 · Cited by 82
Metadata
- Authors
- Khan, M. U., Wang, L., Liu, Z., Gao, Z., Wang, S., Li, H., Zhang, W., Wang, M., Wang, Z., Ma, C., & Zeng, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-05-02
- Volume
- 55
- Issue
- 33
- Pages
- 9548-9552
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2345366910
- Cited by
- 210
- References
- 3
- FWCI
- 7.89
- Type
- journal article
- Language
- en
- Open access
- closed
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- Khan, M. U., Wang, L., Liu, Z., Gao, Z., Wang, S., Li, H., Zhang, W., Wang, M., Wang, Z., Ma, C., & Zeng, J. (2016). Pt3Co Octapods as Superior Catalysts of CO2 Hydrogenation. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201602512
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