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Few‐Layer Antimonene by Liquid‐Phase Exfoliation

Open access
Gibaja, Carlos, Rodriguez‐San‐Miguel, David, Ares, Pablo, Gómez‐Herrero, Julio, Varela, Maria, Gillen, Roland, Maultzsch, Janina, Hauke, Frank, Hirsch, Andreas, Abellán, Gonzalo, Zamora, Félix·2016·Angewandte Chemie International Edition

Abstract

We report on a fast and simple method to produce highly stable isopropanol/water (4:1) suspensions of few‐layer antimonene by liquid‐phase exfoliation of antimony crystals in a process that is assisted by sonication but does not require the addition of any surfactant. This straightforward method generates dispersions of few‐layer antimonene suitable for on‐surface isolation. Analysis by atomic force microscopy, scanning transmission electron microscopy, and electron energy loss spectroscopy confirmed the formation of high‐quality few‐layer antimonene nanosheets with large lateral dimensions. These nanolayers are extremely stable under ambient conditions. Their Raman signals are strongly thickness‐dependent, which was rationalized by means of density functional theory calculations.

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Metadata

Authors
Gibaja, C., Rodriguez‐San‐Miguel, D., Ares, P., Gómez‐Herrero, J., Varela, M., Gillen, R., Maultzsch, J., Hauke, F., Hirsch, A., Abellán, G., & Zamora, F.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2016-08-16
Volume
55
Issue
46
Pages
14345-14349
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2515369844
Cited by
415
References
4
FWCI
25.32
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Few‐Layer Antimonene by Liquid‐Phase Exfoliation. https://app.cochat.ai/papers/10.1002/anie.201605298
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Gibaja, C., Rodriguez‐San‐Miguel, D., Ares, P., Gómez‐Herrero, J., Varela, M., Gillen, R., Maultzsch, J., Hauke, F., Hirsch, A., Abellán, G., & Zamora, F. (2016). Few‐Layer Antimonene by Liquid‐Phase Exfoliation. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201605298

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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