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An Aqueous Symmetric Sodium‐Ion Battery with NASICON‐Structured Na3MnTi(PO4)3
Abstract
A symmetric sodium‐ion battery with an aqueous electrolyte is demonstrated; it utilizes the NASICON‐structured Na 3 MnTi(PO 4)3 as both the anode and the cathode. The NASICON‐structured Na 3 MnTi(PO 4)3 possesses two electrochemically active transition metals with the redox couples of Ti 4+/Ti 3+ and Mn 3+/Mn 2+ working on the anode and cathode sides, respectively. The symmetric cell based on this bipolar electrode material exhibits a well‐defined voltage plateau centered at about 1.4 V in an aqueous electrolyte with a stable cycle performance and superior rate capability. The advent of aqueous symmetric sodium‐ion battery with high safety and low cost may provide a solution for large‐scale stationary energy storage.
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Cites
Lithium Batteries: Status, Prospects and Future
Scrosati, B., & Garche, J. (2010) · Journal of Power Sources · doi:10.1016/j.jpowsour.2009.11.048 · Cited by 5,153
Cited by
Opportunities and Challenges for Organic Electrodes in Electrochemical Energy Storage
Poizot, P., Gaubicher, J., Renault, S., Dubois, L., Liang, Y., & Yao, Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00482 · Cited by 963
Surface-substituted Prussian blue analogue cathode for sustainable potassium-ion batteries
Ge, J., Fan, L., Rao, A. M., Zhou, J., & Lu, B. (2021) · Nature Sustainability · doi:10.1038/s41893-021-00810-7 · Cited by 544
Zhang, J., Wang, D.-W., Lv, W., Zhang, S., Liang, Q., Zheng, D., Kang, F., & Yang, Q.-H. (2017) · Energy & Environmental Science · doi:10.1039/c6ee03367a · Cited by 508
Eshetu, G. G., Elia, G. A., Armand, M., Forsyth, M., Komaba, S., Rojo, T., & Passerini, S. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202000093 · Cited by 470
Aqueous Batteries Operated at −50 °C
Nian, Q., Wang, J., Liu, S., Sun, T., Zheng, S., Zhang, Y., Tao, Z., & Chen, J. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201908913 · Cited by 426
Metadata
- Authors
- Gao, H., & Goodenough, J. B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-09-13
- Volume
- 55
- Issue
- 41
- Pages
- 12768-12772
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2520783495
- Cited by
- 307
- References
- 1
- FWCI
- 13.11
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gao, H., & Goodenough, J. B. (2016). An Aqueous Symmetric Sodium‐Ion Battery with NASICON‐Structured Na3MnTi(PO4)3. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201606508
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