The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Polystyrene Sulfonate Threaded through a Metal–Organic Framework Membrane for Fast and Selective Lithium‐Ion Separation
Abstract
Extraction of lithium ions from salt‐lake brines is very important to produce lithium compounds. Herein, we report a new approach to construct polystyrene sulfonate (PSS) threaded HKUST‐1 metal–organic framework (MOF) membranes through an in situ confinement conversion process. The resulting membrane PSS@HKUST‐1‐6.7, with unique anchored three‐dimensional sulfonate networks, shows a very high Li+ conductivity of 5.53×10−4 S cm−1 at 25 °C, 1.89×10−3 S cm−1 at 70 °C, and Li+ flux of 6.75 mol m−2 h−1, which are five orders higher than that of the pristine HKUST‐1 membrane. Attributed to the different size sieving effects and the affinity differences of the Li+, Na+, K+, and Mg 2+ ions to the sulfonate groups, the PSS@HKUST‐1‐6.7 membrane exhibits ideal selectivities of 78, 99, and 10296 for Li+/Na+, Li+/K+, Li+/Mg 2+ and real binary ion selectivities of 35, 67, and 1815, respectively, the highest ever reported among ionic conductors and Li+ extraction membranes.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Recovery of lithium from Uyuni salar brine
An, J. W., Kang, D. J., Tran, K. T., Kim, M. J., Lim, T., & Tran, T. (2012) · Hydrometallurgy · doi:10.1016/j.hydromet.2012.02.008 · Cited by 509
Somrani, A., Hamzaoui, A. H., & Pontie, M. (2013) · Desalination · doi:10.1016/j.desal.2013.03.009 · Cited by 388
Study on extraction of lithium from salt-lake brine by membrane electrolysis
Liu, X., Chen, X., He, L., & Zhao, Z. (2015) · Desalination · doi:10.1016/j.desal.2015.08.013 · Cited by 176
Song, J., Li, X.-M., Zhang, Y., Yin, Y., Zhao, B., Li, C., Kong, D., & He, T. (2014) · Journal of Membrane Science · doi:10.1016/j.memsci.2014.08.010 · Cited by 75
Cited by
Membrane-based technologies for lithium recovery from water lithium resources: A review
Li, X., Mo, Y., Qing, W., Shao, S., Tang, C. Y., & Li, J. (2019) · Journal of Membrane Science · doi:10.1016/j.memsci.2019.117317 · Cited by 756
Sun, Y., Wang, Q., Wang, Y., Yun, R., & Xiang, X. (2021) · Separation and Purification Technology · doi:10.1016/j.seppur.2020.117807 · Cited by 685
Design principles of ion selective nanostructured membranes for the extraction of lithium ions
Razmjou, A., Asadnia, M., Hosseini, E., Habibnejad Korayem, A., & Chen, V. (2019) · Nature Communications · doi:10.1038/s41467-019-13648-7 · Cited by 616
Extraction of lithium from Chinese salt-lake brines by membranes: Design and practice
Xu, S., Song, J., Bi, Q., Chen, Q., Zhang, W.-M., Qian, Z., Zhang, L., Xu, S., Tang, N., & He, T. (2021) · Journal of Membrane Science · doi:10.1016/j.memsci.2021.119441 · Cited by 462
Lithium extraction from low-quality brines
Yang, S., Wang, Y., Pan, H., He, P., & Zhou, H. (2024) · Nature · doi:10.1038/s41586-024-08117-1 · Cited by 412
Metadata
- Authors
- Guo, Y., Ying, Y., Mao, Y., Peng, X., & Chen, B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-11-02
- Volume
- 55
- Issue
- 48
- Pages
- 15120-15124
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2543606342
- Cited by
- 421
- References
- 5
- FWCI
- 10.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Guo, Y., Ying, Y., Mao, Y., Peng, X., & Chen, B. (2016). Polystyrene Sulfonate Threaded through a Metal–Organic Framework Membrane for Fast and Selective Lithium‐Ion Separation. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201607329
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