The DOI matches its Crossref record.
New Design of a Disulfurating Reagent: Facile and Straightforward Pathway to Unsymmetrical Disulfanes by Copper‐Catalyzed Oxidative Cross‐Coupling
Abstract
A novel reagent, which introduces two sulfur atoms in one step, was designed and used for the construction of diverse disulfanes by copper‐catalyzed oxidative cross‐coupling under mild reaction conditions. By applying this stable and readily prepared reagent, late‐stage modification of pharmaceuticals and natural products can be achieved straightforward. The scaled‐up experiments further indicated the practicality of this protocol. The pH value of the system plays a key role in achieving highly selective cleavage of the C−S bond instead of a S−S bond in the transformation.
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Citations
Cited by
Construction of Thioamide Peptides from Chiral Amino Acids
Liao, Y., Zhang, S., & Jiang, X. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202303625 · Cited by 27
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Metadata
- Authors
- Xiao, X., Feng, M., & Jiang, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-10-11
- Volume
- 55
- Issue
- 45
- Pages
- 14121-14125
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2531134286
- Cited by
- 227
- References
- 0
- FWCI
- 8.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: New Design of a Disulfurating Reagent: Facile and Straightforward Pathway to Unsymmetrical Disulfanes by Copper‐Catalyzed Oxidative Cross‐Coupling. https://app.cochat.ai/papers/10.1002/anie.201608011
- The paper
- Xiao, X., Feng, M., & Jiang, X. (2016). New Design of a Disulfurating Reagent: Facile and Straightforward Pathway to Unsymmetrical Disulfanes by Copper‐Catalyzed Oxidative Cross‐Coupling. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201608011
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
