The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Graphene Oxide Restricts Growth and Recrystallization of Ice Crystals
Abstract
We show graphene oxide (GO) greatly suppresses the growth and recrystallization of ice crystals, and ice crystals display a hexagonal shape in the GO dispersion. Preferred adsorption of GO on the ice crystal surface in liquid water leads to curved ice crystal surface. Therefore, the growth of ice crystal is suppressed owing to the Gibbs–Thompson effect, that is, the curved surface lowers the freezing temperature. Molecular dynamics simulation analysis reveals that oxidized groups on the basal plane of GO form more hydrogen bonds with ice in comparison with liquid water because of the honeycomb hexagonal scaffold of graphene, giving a molecular‐level mechanism for controlling ice formation. Application of GO for cryopreservation shows that addition of only 0.01 wt % of GO to a culture medium greatly increases the motility (from 24.3 % to 71.3 %) of horse sperms. This work reports the control of growth of ice with GO, and opens a new avenue for the application of 2D materials.
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Cites
Graphene: Status and Prospects
Geim, A. K. (2009) · Science · doi:10.1126/science.1158877 · Cited by 13,942
The chemistry of graphene oxide
Dreyer, D. R., Park, S., Bielawski, C. W., & Ruoff, R. S. (2010) · Chem. Soc. Rev. · doi:10.1039/b917103g · Cited by 11,653
Cited by
2D/2D Heterojunction of Ultrathin MXene/Bi2WO6 Nanosheets for Improved Photocatalytic CO2 Reduction
Cao, S., Shen, B., Tong, T., Fu, J., & Yu, J. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201800136 · Cited by 1,543
Zhang, P., Li, J., Lv, L., Zhao, Y., & Qu, L. (2017) · ACS Nano · doi:10.1021/acsnano.7b01965 · Cited by 1,081
Recent progress in the anti-icing performance of slippery liquid-infused surfaces
Heydarian, S., Jafari, R., & Momen, G. (2021) · Progress in Organic Coatings · doi:10.1016/j.porgcoat.2020.106096 · Cited by 117
Cao, Y., Hassan, M., Cheng, Y., Chen, Z., Wang, M., Zhang, X., Haider, Z., & Zhao, G. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b02887 · Cited by 54
Metadata
- Authors
- Geng, H., Liu, X., Shi, G., Bai, G., Ma, J., Chen, J., Wu, Z., Song, Y., Fang, H., & Wang, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-12-15
- Volume
- 56
- Issue
- 4
- Pages
- 997-1001
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2563476458
- Cited by
- 278
- References
- 2
- FWCI
- 11.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- Geng, H., Liu, X., Shi, G., Bai, G., Ma, J., Chen, J., Wu, Z., Song, Y., Fang, H., & Wang, J. (2017). Graphene Oxide Restricts Growth and Recrystallization of Ice Crystals. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201609230
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