Cited by 187Advancements in Battery MaterialsSupercapacitor Materials and FabricationAqueous and Flow Batteries

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Double‐Helix Structure in Carrageenan–Metal Hydrogels: A General Approach to Porous Metal Sulfides/Carbon Aerogels with Excellent Sodium‐Ion Storage

Abstract

The metal sulfide-carbon nanocomposite is a new class of anode material for sodium ion batteries, but its development is restricted by its relative poor rate ability and cyclic stability. Herein, we report the use of double-helix structure of carrageenan-metal hydrogels for the synthesis of 3D metal sulfide (M x S y ) nanostructure/carbon aerogels (CAs) for high-performance sodium-ion storage. The method is unique, and can be used to make multiple M x S y /CAs (such as FeS/CA, Co 9 S 8 /CA, Ni 3 S 4 /CA, CuS/CA, ZnS/CA, and CdS/CA) with ultra-small nanoparticles and hierarchical porous structure by pyrolyzing the carrageenan-metal hydrogels. The as-prepared FeS/CA exhibits a high reversible capacity and excellent cycling stability (280 mA h -1 at 0.5 A g -1 over 200 cycles) and rate performance (222 mA h -1 at 5 A g -1 ) when used as the anode material for sodium-ion batteries. The work shows the value of biomass-derived metal sulfide-carbon heterostuctures in sodium-ion storage.

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Crossref · 10.1002/anie.201610301

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  • Depositing catalysts on conductive carbon substrates with interconnected porous structure achieves accessibility of HER- and OER-relevant reactants with the catalytic centers.

    “the catalysts could be deposited on conductive carbon substrates that have interconnected porous structure to achieve accessibility of HER- and OER-relevant reactants with the catalytic centers.25,26”

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Research works printed but not linked: 29

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Metadata

Authors
Li, D., Yang, D., Yang, X., Wang, Y., Guo, Z., Xia, Y., Sun, S., & Guo, S.
Affiliations
  • Qingdao University (CN)
  • South China University of Technology (CN)
  • China University of Petroleum, East China (CN)
  • Peking University (CN)
Corresponding author
  • Yang, Dongjiang
  • Xia, Yanzhi
  • Guo, Shaojun
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2016-11-23
Volume
55
Issue
51
Pages
15925-15928
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2556737969
Cited by
187
References
0
Citations by year
2026: 4 · 2025: 9 · 2024: 14 · 2023: 16 · 2022: 14 · 2021: 21 · 2020: 25 · 2019: 36 · 2018: 29 · 2017: 19
FWCI
12.90
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
  • Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Aqueous and Flow Batteries
Keywords
DNA double helix, sodium-ion battery anodes, hierarchical porous nanostructures, biomass-derived carbon, heterostructures, pyrolysis, cycling stability, rate capability

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