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Double‐Helix Structure in Carrageenan–Metal Hydrogels: A General Approach to Porous Metal Sulfides/Carbon Aerogels with Excellent Sodium‐Ion Storage
Abstract
The metal sulfide-carbon nanocomposite is a new class of anode material for sodium ion batteries, but its development is restricted by its relative poor rate ability and cyclic stability. Herein, we report the use of double-helix structure of carrageenan-metal hydrogels for the synthesis of 3D metal sulfide (M x S y ) nanostructure/carbon aerogels (CAs) for high-performance sodium-ion storage. The method is unique, and can be used to make multiple M x S y /CAs (such as FeS/CA, Co 9 S 8 /CA, Ni 3 S 4 /CA, CuS/CA, ZnS/CA, and CdS/CA) with ultra-small nanoparticles and hierarchical porous structure by pyrolyzing the carrageenan-metal hydrogels. The as-prepared FeS/CA exhibits a high reversible capacity and excellent cycling stability (280 mA h -1 at 0.5 A g -1 over 200 cycles) and rate performance (222 mA h -1 at 5 A g -1 ) when used as the anode material for sodium-ion batteries. The work shows the value of biomass-derived metal sulfide-carbon heterostuctures in sodium-ion storage.
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Depositing catalysts on conductive carbon substrates with interconnected porous structure achieves accessibility of HER- and OER-relevant reactants with the catalytic centers.
“the catalysts could be deposited on conductive carbon substrates that have interconnected porous structure to achieve accessibility of HER- and OER-relevant reactants with the catalytic centers.25,26”
From Electronic Structure Tuning in Ni3FeN/r-GO Aerogel toward Bifunctional Electrocatalyst for Overall Water Splitting (2018) · cites this paper as [26]
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Gu, Y., Chen, S., Ren, J., Jia, Y. A., Chen, C., Komarneni, S., Yang, D., & Yao, X. (2018) · ACS Nano · doi:10.1021/acsnano.7b05971 · Cited by 540
Self-citationWu, Z., Shi, W., Ding, H., Zhong, B., Huang, W., Zhou, Y., Gui, X., Xie, X., & Wu, J. (2021) · Journal of Materials Chemistry C · doi:10.1039/d1tc02506f · Cited by 121
Aerogels-Inspired based Photo and Electrocatalyst for Water Splitting to Produce Hydrogen
Al-Hamamre, Z., Karimzadeh, Z., Ji, S., Choi, H., & Maleki, H. (2022) · Applied Materials Today · doi:10.1016/j.apmt.2022.101670 · Cited by 18
Metadata
- Authors
- Li, D., Yang, D., Yang, X., Wang, Y., Guo, Z., Xia, Y., Sun, S., & Guo, S.
- Affiliations
- Qingdao University (CN)
- South China University of Technology (CN)
- China University of Petroleum, East China (CN)
- Peking University (CN)
- Corresponding author
- Yang, Dongjiang
- Xia, Yanzhi
- Guo, Shaojun
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-11-23
- Volume
- 55
- Issue
- 51
- Pages
- 15925-15928
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2556737969
- Cited by
- 187
- References
- 0
- Citations by year
- 2026: 4 · 2025: 9 · 2024: 14 · 2023: 16 · 2022: 14 · 2021: 21 · 2020: 25 · 2019: 36 · 2018: 29 · 2017: 19
- FWCI
- 12.90
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Aqueous and Flow Batteries
- Keywords
- DNA double helix, sodium-ion battery anodes, hierarchical porous nanostructures, biomass-derived carbon, heterostructures, pyrolysis, cycling stability, rate capability
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