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Au/La2Ti2O7 Nanostructures Sensitized with Black Phosphorus for Plasmon‐Enhanced Photocatalytic Hydrogen Production in Visible and Near‐Infrared Light

Zhu, Mingshan, Cai, Xiaoyan, Fujitsuka, Mamoru, Zhang, Junying, Majima, Tetsuro·2017·Angewandte Chemie International Edition

Abstract

Efficient utilization of solar energy is a high‐priority target and the search for suitable materials as photocatalysts that not only can harvest the broad wavelength of solar light, from UV to near‐infrared (NIR) region, but also can achieve high and efficient solar‐to‐hydrogen conversion is one of the most challenging missions. Herein, using Au/La 2 Ti 2 O 7 (BP‐Au/LTO) sensitized with black phosphorus (BP), a broadband solar response photocatalyst was designed and used as efficient photocatalyst for H 2 production. The optimum H 2 production rates of BP‐Au/LTO were about 0.74 and 0.30 mmol g−1 h−1 at wavelengths longer than 420 nm and 780 nm, respectively. The broad absorption of BP and plasmonic Au contribute to the enhanced photocatalytic activity in the visible and NIR light regions. Time‐resolved diffuse reflectance spectroscopy revealed efficient interfacial electron transfer from excited BP and Au to LTO which is in accordance with the observed high photoactivities.

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Metadata

Authors
Zhu, M., Cai, X., Fujitsuka, M., Zhang, J., & Majima, T.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2017-01-12
Volume
56
Issue
8
Pages
2064-2068
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2571933314
Cited by
335
References
1
FWCI
13.45
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Au/La2Ti2O7 Nanostructures Sensitized with Black Phosphorus for Plasmon‐Enhanced Photocatalytic Hydrogen Production in Visible and Near‐Infrared Light. https://app.cochat.ai/papers/10.1002/anie.201612315
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Zhu, M., Cai, X., Fujitsuka, M., Zhang, J., & Majima, T. (2017). Au/La2Ti2O7 Nanostructures Sensitized with Black Phosphorus for Plasmon‐Enhanced Photocatalytic Hydrogen Production in Visible and Near‐Infrared Light. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201612315

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