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Lithiophilic Sites in Doped Graphene Guide Uniform Lithium Nucleation for Dendrite‐Free Lithium Metal Anodes

Zhang, Rui, Chen, Xiao‐Ru, Chen, Xiang, Cheng, Xin‐Bing, Zhang, Xue‐Qiang, Yan, Chong, Zhang, Qiang·2017·Angewandte Chemie International Edition

Abstract

Lithium (Li) metal is the most promising electrode for next‐generation rechargeable batteries. However, the challenges induced by Li dendrites on a working Li metal anode hinder the practical applications of Li metal batteries. Herein, nitrogen (N) doped graphene was adopted as the Li plating matrix to regulate Li metal nucleation and suppress dendrite growth. The N‐containing functional groups, such as pyridinic and pyrrolic nitrogen in the N‐doped graphene, are lithiophilic, which guide the metallic Li nucleation causing the metal to distribute uniformly on the anode surface. As a result, the N‐doped graphene modified Li metal anode exhibits a dendrite‐free morphology during repeated Li plating and demonstrates a high Coulombic efficiency of 98 % for near 200 cycles.

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Metadata

Authors
Zhang, R., Chen, X., Chen, X., Cheng, X., Zhang, X., Yan, C., & Zhang, Q.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2017-05-03
Volume
56
Issue
27
Pages
7764-7768
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2611684284
Cited by
1,225
References
1
FWCI
61.64
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Lithiophilic Sites in Doped Graphene Guide Uniform Lithium Nucleation for Dendrite‐Free Lithium Metal Anodes. https://app.cochat.ai/papers/10.1002/anie.201702099
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Zhang, R., Chen, X., Chen, X., Cheng, X., Zhang, X., Yan, C., & Zhang, Q. (2017). Lithiophilic Sites in Doped Graphene Guide Uniform Lithium Nucleation for Dendrite‐Free Lithium Metal Anodes. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201702099

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