The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Betaine Catalysis for Hierarchical Reduction of CO2 with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines
Abstract
An efficient, sustainable organocatalyst, glycine betaine, was developed for the reductive functionalization of CO 2 with amines and diphenylsilane. Methylamines and formamides were obtained in high yield by tuning the CO 2 pressure and reaction temperature. Based on identification of the key intermediate, that is, the aminal, an alternative mechanism for methylation involving the C 0 silyl acetal and aminal is proposed. Furthermore, reducing the CO 2 amount afforded aminals with high yield and selectivity. Therefore, betaine catalysis affords products with a diversified energy content that is, formamides, aminals and methylamines, by hierarchical two‐, four‐ and six‐electron reduction, respectively, of CO 2 coupled with C−N bond formation.
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Cites
Comprehensive Analysis of mRNA Methylation Reveals Enrichment in 3′ UTRs and near Stop Codons
Meyer, K. D., Saletore, Y., Zumbo, P., Elemento, O., Mason, C. E., & Jaffrey, S. R. (2012) · Cell · doi:10.1016/j.cell.2012.05.003 · Cited by 4,223
Carbon dioxide utilization with C–N bond formation: carbon dioxide capture and subsequent conversion
Yang, Z.-Z., He, L.-N., Gao, J., Liu, A.-H., & Yu, B. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02774g · Cited by 520
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Cited by
Cheng, Z., Wang, X., Yang, H., Yu, X., Lin, Q., Hu, Q., & He, C. (2021) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2020.04.018 · Cited by 33
Metadata
- Authors
- Liu, X., Li, X., Qiao, C., Fu, H., & He, L.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-05-24
- Volume
- 56
- Issue
- 26
- Pages
- 7425-7429
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2610748134
- Cited by
- 221
- References
- 2
- FWCI
- 8.19
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, X., Li, X., Qiao, C., Fu, H., & He, L. (2017). Betaine Catalysis for Hierarchical Reduction of CO2 with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201702734
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