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Cited by 196

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From a Molecular 2Fe‐2Se Precursor to a Highly Efficient Iron Diselenide Electrocatalyst for Overall Water Splitting

Panda, Chakadola, Menezes, Prashanth W., Walter, Carsten, Yao, Shenglai, Miehlich, Matthias E., Gutkin, Vitaly, Meyer, Karsten, Driess, Matthias·2017·Angewandte Chemie International Edition

Abstract

A highly active FeSe 2 electrocatalyst for durable overall water splitting was prepared from a molecular 2Fe‐2Se precursor. The as‐synthesized FeSe 2 was electrophoretically deposited on nickel foam and applied to the oxygen and hydrogen evolution reactions (OER and HER, respectively) in alkaline media. When used as an oxygen‐evolution electrode, a low 245 mV overpotential was achieved at a current density of 10 mA cm−2, representing outstanding catalytic activity and stability because of Fe(OH)2/FeOOH active sites formed at the surface of FeSe 2. Remarkably, the system is also favorable for the HER. Moreover, an overall water‐splitting setup was fabricated using a two‐electrode cell, which displayed a low cell voltage and high stability. In summary, the first iron selenide material is reported that can be used as a bifunctional electrocatalyst for the OER and HER, as well as overall water splitting.

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Metadata

Authors
Panda, C., Menezes, P. W., Walter, C., Yao, S., Miehlich, M. E., Gutkin, V., Meyer, K., & Driess, M.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2017-07-19
Volume
56
Issue
35
Pages
10506-10510
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2732244883
Cited by
196
References
5
FWCI
6.40
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: From a Molecular 2Fe‐2Se Precursor to a Highly Efficient Iron Diselenide Electrocatalyst for Overall Water Splitting. https://app.cochat.ai/papers/10.1002/anie.201706196
The paper
Panda, C., Menezes, P. W., Walter, C., Yao, S., Miehlich, M. E., Gutkin, V., Meyer, K., & Driess, M. (2017). From a Molecular 2Fe‐2Se Precursor to a Highly Efficient Iron Diselenide Electrocatalyst for Overall Water Splitting. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201706196

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