The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Atomic‐Level Insight into Optimizing the Hydrogen Evolution Pathway over a Co1‐N4 Single‐Site Photocatalyst
Abstract
Knowledge of the photocatalytic H 2 evolution mechanism is of great importance for designing active catalysts toward a sustainable energy supply. An atomic‐level insight, design, and fabrication of single‐site Co 1‐N 4 composite as a prototypical photocatalyst for efficient H 2 production is reported. Correlated atomic characterizations verify that atomically dispersed Co atoms are successfully grafted by covalently forming a Co 1‐N 4 structure on g‐C 3 N 4 nanosheets by atomic layer deposition. Different from the conventional homolytic or heterolytic pathway, theoretical investigations reveal that the coordinated donor nitrogen increases the electron density and lowers the formation barrier of key Co hydride intermediate, thereby accelerating H–H coupling to facilitate H 2 generation. As a result, the composite photocatalyst exhibits a robust H 2 production activity up to 10.8 μmol h−1, 11 times higher than that of pristine counterpart.
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Cited by
Cao, L., Luo, Q., Liu, W., Lin, Y., Liu, X., Cao, Y., Zhang, W., Wu, Y., Yang, J., Yao, T., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0203-5 · Cited by 901
Self-citationCui, T., Wang, Y., Ye, T., Wu, J., Chen, Z., Li, J., Lei, Y., Wang, D., & Li, Y. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202115219 · Cited by 659
Single-atom Rh/N-doped carbon electrocatalyst for formic acid oxidation
Xiong, Y., Dong, J., Huang, Z.-Q., Xin, P., Chen, W., Wang, Y., Li, Z., Jin, Z., Xing, W., Zhuang, Z., et al. (2020) · Nature Nanotechnology · doi:10.1038/s41565-020-0665-x · Cited by 610
Xiao, X., Gao, Y., Zhang, L., Zhang, J., Zhang, Q., Li, Q., Bao, H., Zhou, J., Miao, S., Chen, N., et al. (2020) · Advanced Materials · doi:10.1002/adma.202003082 · Cited by 528
Zhao, Y., Waterhouse, G. I. N., Chen, G., Xiong, X., Wu, L.-Z., Tung, C.-H., & Zhang, T. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00607e · Cited by 435
Metadata
- Authors
- Cao, Y., Chen, S., Luo, Q., Yan, H., Lin, Y., Liu, W., Cao, L., Lu, J., Yang, J., Yao, T., & Wei, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-08-28
- Volume
- 56
- Issue
- 40
- Pages
- 12191-12196
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2742542637
- Cited by
- 359
- References
- 34
- FWCI
- 8.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- Cao, Y., Chen, S., Luo, Q., Yan, H., Lin, Y., Liu, W., Cao, L., Lu, J., Yang, J., Yao, T., & Wei, S. (2017). Atomic‐Level Insight into Optimizing the Hydrogen Evolution Pathway over a Co1‐N4 Single‐Site Photocatalyst. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201706467
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