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Macroscopic Polarization Enhancement Promoting Photo‐ and Piezoelectric‐Induced Charge Separation and Molecular Oxygen Activation

Huang, Hongwei, Tu, Shuchen, Zeng, Chao, Zhang, Tierui, Reshak, Ali H., Zhang, Yihe·2017·Angewandte Chemie International Edition

Abstract

Efficient photo‐ and piezoelectric‐induced molecular oxygen activation are both achieved by macroscopic polarization enhancement on a noncentrosymmetric piezoelectric semiconductor BiOIO 3. The replacement of V 5+ions for I 5+in IO 3 polyhedra gives rise to strengthened macroscopic polarization of BiOIO 3, which facilitates the charge separation in the photocatalytic and piezoelectric catalytic process, and renders largely promoted photo‐ and piezoelectric induced reactive oxygen species (ROS) evolution, such as superoxide radicals (.O 2−) and hydroxyl radicals (.OH). This work advances piezoelectricity as a new route to efficient ROS generation, and also discloses macroscopic polarization engineering on improvement of multi‐responsive catalysis.

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Metadata

Authors
Huang, H., Tu, S., Zeng, C., Zhang, T., Reshak, A. H., & Zhang, Y.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2017-08-16
Volume
56
Issue
39
Pages
11860-11864
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2737707228
Cited by
1,041
References
1
FWCI
40.92
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Macroscopic Polarization Enhancement Promoting Photo‐ and Piezoelectric‐Induced Charge Separation and Molecular Oxygen Activation. https://app.cochat.ai/papers/10.1002/anie.201706549
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Huang, H., Tu, S., Zeng, C., Zhang, T., Reshak, A. H., & Zhang, Y. (2017). Macroscopic Polarization Enhancement Promoting Photo‐ and Piezoelectric‐Induced Charge Separation and Molecular Oxygen Activation. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201706549

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