The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
A Stable Nanocobalt Catalyst with Highly Dispersed CoNx Active Sites for the Selective Dehydrogenation of Formic Acid
Abstract
Novel nanostructured catalysts with highly dispersed cobalt have been synthesized by the pyrolysis of metal phenanthroline complexes. Materials with significantly different properties were obtained by simply tuning the metal/ligand ratio. The catalytic potential of this class of compounds is shown by the first example of the dehydrogenation of formic acid under the catalysis of atomically dispersed cobalt. From TEM, XPS, and XRD characterization, KSCN poisoning, and acid leaching, the formation of CoN x species as the active site seems key to the success of this reaction. Excellent stability and recyclability make this new catalyst also attractive for other applications.
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Citations
Cites
Opportunities and challenges for a sustainable energy future
Chu, S., & Majumdar, A. (2012) · Nature · doi:10.1038/nature11475 · Cited by 12,550
Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst
Boddien, A., Mellmann, D., Gärtner, F., Jackstell, R., Junge, H., Dyson, P. J., Laurenczy, G., Ludwig, R., & Beller, M. (2011) · Science · doi:10.1126/science.1206613 · Cited by 832
Self-citationMolecular metal–Nx centres in porous carbon for electrocatalytic hydrogen evolution
Liang, H.-W., Brüller, S., Dong, R., Zhang, J., Feng, X., & Müllen, K. (2015) · Nature Communications · doi:10.1038/ncomms8992 · Cited by 655
Metadata
- Authors
- Tang, C., Surkus, A., Chen, F., Pohl, M., Agostini, G., Schneider, M., Junge, H., & Beller, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-11-30
- Volume
- 56
- Issue
- 52
- Pages
- 16616-16620
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2784842168
- Cited by
- 188
- References
- 3
- FWCI
- 5.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tang, C., Surkus, A., Chen, F., Pohl, M., Agostini, G., Schneider, M., Junge, H., & Beller, M. (2017). A Stable Nanocobalt Catalyst with Highly Dispersed CoNx Active Sites for the Selective Dehydrogenation of Formic Acid. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201710766
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