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Hierarchical Hollow Nanoprisms Based on Ultrathin Ni‐Fe Layered Double Hydroxide Nanosheets with Enhanced Electrocatalytic Activity towards Oxygen Evolution

Open access
Yu, Le, Yang, Jing Fan, Guan, Bu Yuan, Lu, Yan, Lou, Xiong Wen (David)·2018·Angewandte Chemie International Edition

Abstract

The oxygen evolution reaction (OER) is involved in various renewable energy systems, such as water‐splitting cells and metal–air batteries. Ni‐Fe layered double hydroxides (LDHs) have been reported as promising OER electrocatalysts in alkaline electrolytes. The rational design of advanced nanostructures for Ni‐Fe LDHs is highly desirable to optimize their electrocatalytic performance. Herein, we report a facile self‐templated strategy for the synthesis of novel hierarchical hollow nanoprisms composed of ultrathin Ni‐Fe LDH nanosheets. Tetragonal nanoprisms of nickel precursors were first synthesized as the self‐sacrificing template. Afterwards, these Ni precursors were consumed during the hydrolysis of iron(II) sulfate for the simultaneous growth of a layer of Ni‐Fe LDH nanosheets on the surface. The resultant Ni‐Fe LDH hollow prisms with large surface areas manifest high electrocatalytic activity towards the OER with low overpotential, small Tafel slope, and remarkable stability.

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Metadata

Authors
Yu, L., Yang, J. F., Guan, B. Y., Lu, Y., & Lou, X. W. (.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2017-12-14
Volume
57
Issue
1
Pages
172-176
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2769127768
Cited by
602
References
7
FWCI
19.36
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Hierarchical Hollow Nanoprisms Based on Ultrathin Ni‐Fe Layered Double Hydroxide Nanosheets with Enhanced Electrocatalytic Activity towards Oxygen Evolution. https://app.cochat.ai/papers/10.1002/anie.201710877
The paper
Yu, L., Yang, J. F., Guan, B. Y., Lu, Y., & Lou, X. W. (. (2018). Hierarchical Hollow Nanoprisms Based on Ultrathin Ni‐Fe Layered Double Hydroxide Nanosheets with Enhanced Electrocatalytic Activity towards Oxygen Evolution. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201710877

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.