The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Visible‐Light‐Mediated Metal‐Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si−H Activation
Abstract
Although there has been significant progress in the development of transition‐metal‐catalyzed hydrosilylations of alkenes over the past several decades, metal‐free hydrosilylation is still rare and highly desirable. Herein, we report a convenient visible‐light‐driven metal‐free hydrosilylation of both electron‐deficient and electron‐rich alkenes that proceeds through selective hydrogen atom transfer for Si−H activation. The synergistic combination of the organophotoredox catalyst 4CzIPN with quinuclidin‐3‐yl acetate enabled the hydrosilylation of electron‐deficient alkenes by selective Si−H activation while the hydrosilylation of electron‐rich alkenes was achieved by merging photoredox and polarity‐reversal catalysis.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Cited by
Photocarboxylation of Benzylic C–H Bonds
Meng, Q.-Y., Schirmer, T. E., Berger, A. L., Donabauer, K., & König, B. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b05360 · Cited by 313
Metadata
- Authors
- Zhou, R., Goh, Y. Y., Liu, H., Tao, H., Li, L., & Wu, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-12-04
- Volume
- 56
- Issue
- 52
- Pages
- 16621-16625
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2770297371
- Cited by
- 225
- References
- 1
- FWCI
- 6.74
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Visible‐Light‐Mediated Metal‐Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si−H Activation. https://app.cochat.ai/papers/10.1002/anie.201711250
- The paper
- Zhou, R., Goh, Y. Y., Liu, H., Tao, H., Li, L., & Wu, J. (2017). Visible‐Light‐Mediated Metal‐Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si−H Activation. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201711250
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
