The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
A Long Cycle Life, Self‐Healing Zinc–Iodine Flow Battery with High Power Density
Abstract
A zinc–iodine flow battery (ZIFB) with long cycle life, high energy, high power density, and self‐healing behavior is prepared. The long cycle life was achieved by employing a low‐cost porous polyolefin membrane and stable electrolytes. The pores in the membrane can be filled with a solution containing I 3− that can react with zinc dendrite. Therefore, by consuming zinc dendrite, the battery can self‐recover from micro‐short‐circuiting resulting from overcharging. By using KI, ZnBr 2, and KCl as electrolytes and a high ion‐conductivity porous membrane, a very high power density can be achieved. As a result, a ZIFB exhibits an energy efficiency (EE) of 82 % at 80 mA cm−2, which is 8 times higher than the currently reported ZIFBs. Furthermore, a stack with an output of 700 W was assembled and continuously run for more than 300 cycles. We believe this ZIFB can lead the way to development of new‐generation, high‐performance flow batteries.
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Cites
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The Chemistry of Redox‐Flow Batteries
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Molecular engineering of organic electroactive materials for redox flow batteries
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Ambipolar zinc-polyiodide electrolyte for a high-energy density aqueous redox flow battery
Li, B., Nie, Z., Vijayakumar, M., Li, G., Liu, J., Sprenkle, V., & Wang, W. (2015) · Nature Communications · doi:10.1038/ncomms7303 · Cited by 604
Self-citationNonaqueous redox-flow batteries: organic solvents, supporting electrolytes, and redox pairs
Gong, K., Fang, Q., Gu, S., Li, S. F. Y., & Yan, Y. (2015) · Energy & Environmental Science · doi:10.1039/c5ee02341f · Cited by 470
A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage
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Advanced porous membranes with ultra-high selectivity and stability for vanadium flow batteries
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Self-citationHigh power rechargeable magnesium/iodine battery chemistry
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Cited by
A Metal-Organic Framework Host for Highly Reversible Dendrite-free Zinc Metal Anodes
Wang, Z., Huang, J., Guo, Z., Dong, X., Liu, Y., Wang, Y., & Xia, Y. (2019) · Joule · doi:10.1016/j.joule.2019.02.012 · Cited by 938
Electrochemical Zinc Ion Capacitors: Fundamentals, Materials, and Systems
Yin, J., Zhang, W., Alhebshi, N. A., Salah, N., & Alshareef, H. N. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202100201 · Cited by 325
Metadata
- Authors
- Xie, C., Zhang, H., Xu, W., Wang, W., & Li, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-05-14
- Volume
- 57
- Issue
- 35
- Pages
- 11171-11176
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2799410105
- Cited by
- 253
- References
- 17
- FWCI
- 9.22
- Type
- journal article
- Language
- en
- Open access
- closed
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