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MOF‐Derived Hollow CoS Decorated with CeOx Nanoparticles for Boosting Oxygen Evolution Reaction Electrocatalysis
Abstract
Transition‐metal sulfides (TMSs) have emerged as important candidates for oxygen evolution reaction (OER) electrocatalysts. Now a hybrid nanostructure has been decorated with CeOx nanoparticles on the surface of ZIF‐67‐derived hollow CoS through in situ generation. Proper control of the amount of CeOx on the surface of CoS can achieve precise tuning of Co 2+/Co 3+ ratio, especially for the induced defects, further boosting the OER activity. Meanwhile, the formation of protective CeO x thin layer effectively inhibits the corrosion by losing cobalt ion species from the active surface into the solution. It is thus a rare example of a hybrid hetero‐structural electrocatalyst with CeOx NPs to improve the performance of the hollow TMS nanocage.
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Bao, J., Zhang, X., Fan, B., Zhang, J., Zhou, M., Yang, W., Hu, X., Wang, H., Pan, B., & Xie, Y. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502226 · Cited by 1,428
Cited by
Bavykina, A., Kolobov, N., Khan, I. S., Bau, J. A., Ramirez, A., & Gascon, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00685 · Cited by 1,754
Nanoarchitectonics for Transition‐Metal‐Sulfide‐Based Electrocatalysts for Water Splitting
Guo, Y., Park, T., Yi, J. W., Henzie, J., Kim, J., Wang, Z., Jiang, B., Bando, Y., Sugahara, Y., Tang, J., et al. (2019) · Advanced Materials · doi:10.1002/adma.201807134 · Cited by 1,402
Metal–organic frameworks as a platform for clean energy applications
Li, X., Yang, X., Xue, H., Pang, H., & Xu, Q. (2020) · EnergyChem · doi:10.1016/j.enchem.2020.100027 · Cited by 706
Jadhav, H. S., Bandal, H. A., Ramakrishna, S., & Kim, H. (2022) · Advanced Materials · doi:10.1002/adma.202107072 · Cited by 447
Huang, J., Li, Y., Zhang, Y., Rao, G., Wu, C., Hu, Y., Wang, X., Lu, R., Li, Y., & Xiong, J. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201910716 · Cited by 444
Metadata
- Authors
- Xu, H., Cao, J., Shan, C., Wang, B., Xi, P., Liu, W., & Tang, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-06-12
- Volume
- 57
- Issue
- 28
- Pages
- 8654-8658
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2802414289
- Cited by
- 471
- References
- 1
- FWCI
- 12.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xu, H., Cao, J., Shan, C., Wang, B., Xi, P., Liu, W., & Tang, Y. (2018). MOF‐Derived Hollow CoS Decorated with CeOx Nanoparticles for Boosting Oxygen Evolution Reaction Electrocatalysis. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201804673
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