The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Introducing Fe2+ into Nickel–Iron Layered Double Hydroxide: Local Structure Modulated Water Oxidation Activity
Open accessAbstract
Exploring materials with regulated local structures and understanding how the atomic motifs govern the reactivity and durability of catalysts are a critical challenge for designing advanced catalysts. Herein we report the tuning of the local atomic structure of nickel–iron layered double hydroxides (NiFe‐LDHs) by partially substituting Ni 2+ with Fe 2+ to introduce Fe‐O‐Fe moieties. These Fe 2+‐containing NiFe‐LDHs exhibit enhanced oxygen evolution reaction (OER) activity with an ultralow overpotential of 195 mV at the current density of 10 mA cm−2, which is among the best OER catalytic performance to date. In‐situ X‐ray absorption, Raman, and electrochemical analysis jointly reveal that the Fe‐O‐Fe motifs could stabilize high‐valent metal sites at low overpotentials, thereby enhancing the OER activity. These results reveal the importance of tuning the local atomic structure for designing high efficiency electrocatalysts.
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Cites
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
Cited by
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Li, P., Wang, M., Duan, X., Zheng, L., Cheng, X., Zhang, Y., Kuang, Y., Li, Y., Ma, Q., Feng, Z., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-09666-0 · Cited by 717
Self-citationGong, Q., Ding, P., Xu, M., Zhu, X., Wang, M., Deng, J., Ma, Q., Han, N., Zhu, Y., Lu, J., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-10819-4 · Cited by 678
Self-citationZong, Y., Shao, Y., Zeng, Y., Shao, B., Xu, L., Zhao, Z., Liu, W., & Wu, D. (2021) · Environmental Science & Technology · doi:10.1021/acs.est.1c00375 · Cited by 499
Self-citationPreparation of nickel-iron hydroxides by microorganism corrosion for efficient oxygen evolution
Yang, H., Gong, L., Wang, H., Dong, C., Wang, J., Qi, K., Liu, H., Guo, X., & Xia, B. Y. (2020) · Nature Communications · doi:10.1038/s41467-020-18891-x · Cited by 339
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Metadata
- Authors
- Cai, Z., Zhou, D., Wang, M., Bak, S., Wu, Y., Wu, Z., Tian, Y., Xiong, X., Li, Y., Liu, W., Siahrostami, S., Kuang, Y., Yang, X., Duan, H., Feng, Z., Wang, H., & Sun, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-06-27
- Volume
- 57
- Issue
- 30
- Pages
- 9392-9396
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2808642989
- Cited by
- 398
- References
- 1
- FWCI
- 9.84
- Type
- journal article
- Language
- en
- Open access
- green
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- Cai, Z., Zhou, D., Wang, M., Bak, S., Wu, Y., Wu, Z., Tian, Y., Xiong, X., Li, Y., Liu, W., Siahrostami, S., Kuang, Y., Yang, X., Duan, H., Feng, Z., Wang, H., & Sun, X. (2018). Introducing Fe2+ into Nickel–Iron Layered Double Hydroxide: Local Structure Modulated Water Oxidation Activity. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201804881
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