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Cited by 398

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Introducing Fe2+ into Nickel–Iron Layered Double Hydroxide: Local Structure Modulated Water Oxidation Activity

Open access
Cai, Zhao, Zhou, Daojin, Wang, Maoyu, Bak, Seong‐Min, Wu, Yueshen, Wu, Zishan, Tian, Yang, Xiong, Xuya, Li, Yaping, Liu, Wen, Siahrostami, Samira, Kuang, Yun, Yang, Xiao‐Qing, Duan, Haohong, Feng, Zhenxing, Wang, Hailiang, Sun, Xiaoming·2018·Angewandte Chemie International Edition

Abstract

Exploring materials with regulated local structures and understanding how the atomic motifs govern the reactivity and durability of catalysts are a critical challenge for designing advanced catalysts. Herein we report the tuning of the local atomic structure of nickel–iron layered double hydroxides (NiFe‐LDHs) by partially substituting Ni 2+ with Fe 2+ to introduce Fe‐O‐Fe moieties. These Fe 2+‐containing NiFe‐LDHs exhibit enhanced oxygen evolution reaction (OER) activity with an ultralow overpotential of 195 mV at the current density of 10 mA cm−2, which is among the best OER catalytic performance to date. In‐situ X‐ray absorption, Raman, and electrochemical analysis jointly reveal that the Fe‐O‐Fe motifs could stabilize high‐valent metal sites at low overpotentials, thereby enhancing the OER activity. These results reveal the importance of tuning the local atomic structure for designing high efficiency electrocatalysts.

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Metadata

Authors
Cai, Z., Zhou, D., Wang, M., Bak, S., Wu, Y., Wu, Z., Tian, Y., Xiong, X., Li, Y., Liu, W., Siahrostami, S., Kuang, Y., Yang, X., Duan, H., Feng, Z., Wang, H., & Sun, X.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2018-06-27
Volume
57
Issue
30
Pages
9392-9396
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2808642989
Cited by
398
References
1
FWCI
9.84
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Introducing Fe2+ into Nickel–Iron Layered Double Hydroxide: Local Structure Modulated Water Oxidation Activity. https://app.cochat.ai/papers/10.1002/anie.201804881
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Cai, Z., Zhou, D., Wang, M., Bak, S., Wu, Y., Wu, Z., Tian, Y., Xiong, X., Li, Y., Liu, W., Siahrostami, S., Kuang, Y., Yang, X., Duan, H., Feng, Z., Wang, H., & Sun, X. (2018). Introducing Fe2+ into Nickel–Iron Layered Double Hydroxide: Local Structure Modulated Water Oxidation Activity. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201804881

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