The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Efficient Oxygen Reduction Reaction (ORR) Catalysts Based on Single Iron Atoms Dispersed on a Hierarchically Structured Porous Carbon Framework
Abstract
Single Fe atoms dispersed on hierarchically structured porous carbon (SA‐Fe‐HPC) frameworks are prepared by pyrolysis of unsubstituted phthalocyanine/iron phthalocyanine complexes confined within micropores of the porous carbon support. The single‐atom Fe catalysts have a well‐defined atomic dispersion of Fe atoms coordinated by N ligands on the 3D hierarchically porous carbon support. These SA‐Fe‐HPC catalysts are comparable to the commercial Pt/C electrode even in acidic electrolytes for oxygen reduction reaction (ORR) in terms of the ORR activity (E1/2=0.81 V), but have better long‐term electrochemical stability (7 mV negative shift after 3000 potential cycles) and fuel selectivity. In alkaline media, the SA‐Fe‐HPC catalysts outperform the commercial Pt/C electrode in ORR activity (E1/2=0.89 V), fuel selectivity, and long‐term stability (1 mV negative shift after 3000 potential cycles). Thus, these nSA‐Fe‐HPCs are promising non‐platinum‐group metal ORR catalysts for fuel‐cell technologies.
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Self-citationAn Overview and Future Perspectives of Rechargeable Zinc Batteries
Shi, Y., Chen, Y., Shi, L., Wang, K., Wang, B., Li, L., Ma, Y., Li, Y., Sun, Z., Ali, W., et al. (2020) · Small · doi:10.1002/smll.202000730 · Cited by 389
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Metadata
- Authors
- Zhang, Z., Sun, J., Wang, F., & Dai, L.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-06-19
- Volume
- 57
- Issue
- 29
- Pages
- 9038-9043
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2809416657
- Cited by
- 592
- References
- 8
- FWCI
- 18.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, Z., Sun, J., Wang, F., & Dai, L. (2018). Efficient Oxygen Reduction Reaction (ORR) Catalysts Based on Single Iron Atoms Dispersed on a Hierarchically Structured Porous Carbon Framework. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201804958
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