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Cited by 205

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Hydrogenation of CO2‐Derived Carbonates and Polycarbonates to Methanol and Diols by Metal–Ligand Cooperative Manganese Catalysis

Zubar, Viktoriia, Lebedev, Yury, Azofra, Luis Miguel, Cavallo, Luigi, El‐Sepelgy, Osama, Rueping, Magnus·2018·Angewandte Chemie International Edition

Abstract

The first base‐metal‐catalysed hydrogenation of CO 2‐derived carbonates to alcohols is presented. The reaction proceeds under mild conditions in the presence of a well‐defined manganese complex with a loading as low as 0.25 mol %. The non‐precious‐metal homogenous catalytic system provides an indirect route for the conversion of CO 2 into methanol with the co‐production of value‐added (vicinal) diols in yields of up to 99 %. Experimental and computational studies indicate a metal–ligand cooperative catalysis mechanism.

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Metadata

Authors
Zubar, V., Lebedev, Y., Azofra, L. M., Cavallo, L., El‐Sepelgy, O., & Rueping, M.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2018-09-03
Volume
57
Issue
41
Pages
13439-13443
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2887873388
Cited by
205
References
1
FWCI
7.08
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Hydrogenation of CO2‐Derived Carbonates and Polycarbonates to Methanol and Diols by Metal–Ligand Cooperative Manganese Catalysis. https://app.cochat.ai/papers/10.1002/anie.201805630
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Zubar, V., Lebedev, Y., Azofra, L. M., Cavallo, L., El‐Sepelgy, O., & Rueping, M. (2018). Hydrogenation of CO2‐Derived Carbonates and Polycarbonates to Methanol and Diols by Metal–Ligand Cooperative Manganese Catalysis. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201805630

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