The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Competition between H and CO for Active Sites Governs Copper‐Mediated Electrosynthesis of Hydrocarbon Fuels
Abstract
The dynamics of carbon monoxide on Cu surfaces was investigated during CO reduction, providing insight into the mechanism leading to the formation of hydrogen, methane, and ethylene, the three key products in the electrochemical reduction of CO 2. Reaction order experiments were conducted at low temperature in an ethanol medium affording high solubility and surface‐affinity for carbon monoxide. Surprisingly, the methane production rate is suppressed by increasing the pressure of CO, whereas ethylene production remains largely unaffected. The data show that CH 4 and H 2 production are linked through a common H intermediate and that methane is formed through reactions among adsorbed H and CO, which are in direct competition with each other for surface sites. The data exclude the participation of solution species in rate‐limiting steps, highlighting the importance of increasing surface recombination rates for efficient fuel synthesis.
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Citations
Cites
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Goodpaster, J. D., Bell, A. T., & Head-Gordon, M. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00358 · Cited by 702
Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
Verdaguer-Casadevall, A., Li, C. W., Johansson, T. P., Scott, S. B., McKeown, J. T., Kumar, M., Stephens, I. E. L., Kanan, M. W., & Chorkendorff, I. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06227 · Cited by 645
Murata, A., & Hori, Y. (1991) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.64.123 · Cited by 544
Cited by
Huang, J., Mensi, M., Oveisi, E., Mantella, V., & Buonsanti, R. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.8b12381 · Cited by 594
Solvents and Supporting Electrolytes in the Electrocatalytic Reduction of CO2
König, M., Vaes, J., Klemm, E., & Pant, D. (2019) · iScience · doi:10.1016/j.isci.2019.07.014 · Cited by 429
Constraining CO coverage on copper promotes high-efficiency ethylene electroproduction
Li, J., Wang, Z., McCallum, C., Xu, Y., Li, F., Wang, Y., Gabardo, C. M., Dinh, C.-T., Zhuang, T.-T., Wang, L., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0380-x · Cited by 391
Electrochemical CO2 Reduction: Classifying Cu Facets
Bagger, A., Ju, W., Varela, A. S., Strasser, P., & Rossmeisl, J. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b01899 · Cited by 294
Address the “alkalinity problem” in CO2 electrolysis with catalyst design and translation
Chen, C., Li, Y., & Yang, P. (2021) · Joule · doi:10.1016/j.joule.2021.02.008 · Cited by 258
Metadata
- Authors
- Schreier, M., Yoon, Y., Jackson, M. N., & Surendranath, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-07-13
- Volume
- 57
- Issue
- 32
- Pages
- 10221-10225
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2809274322
- Cited by
- 186
- References
- 4
- FWCI
- 3.90
- Type
- journal article
- Language
- en
- Open access
- closed
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