The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
A Stable Bifunctional Catalyst for Rechargeable Zinc–Air Batteries: Iron–Cobalt Nanoparticles Embedded in a Nitrogen‐Doped 3D Carbon Matrix
Abstract
Low‐cost, efficient bifunctional electrocatalysts are needed to mediate the oxygen reduction and oxygen evolution reactions (ORR/OER) in Zn–air batteries. Such catalysts should offer binary active sites and an ability to transfer oxygen‐based species and electrons. A 3D catalyst, composed of nanoparticles of CoFe alloy embedded in N‐doped carbon nanotubes tangled with reduced graphene oxide, was developed, which presents appreciable ORR/OER activity when applied in a Zn–air battery. A high open‐circuit voltage of 1.43 V, a stable discharge voltage of 1.22 V, a high energy efficiency of 60.1 %, and excellent stability after 1 600 cycles at 10 mA cm−2 are demonstrated. An all‐solid‐state battery had an outstanding lifetime and high cell efficiency even upon bending. In situ X‐ray absorption spectroscopy revealed that OOH* and O* intermediates induce variations in the Fe−Fe and Co−Co bond lengths, respectively, suggesting that Fe and Co species are crucial to the ORR/OER processes.
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Wu, H. B., Xia, B. Y., Yu, L., Yu, X.-Y., & Lou, X. W. (2015) · Nature Communications · doi:10.1038/ncomms7512 · Cited by 1,434
Cited by
Shi, Q., Liu, Q., Ma, Y., Fang, Z., Liang, Z., Shao, G., Tang, B., Yang, W., Qin, L., & Fang, X. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903854 · Cited by 361
Rational Design of Highly Stable and Active MXene‐Based Bifunctional ORR/OER Double‐Atom Catalysts
Wei, B., Fu, Z., Legut, D., Germann, T. C., Du, S., Zhang, H., Francisco, J. S., & Zhang, R. (2021) · Advanced Materials · doi:10.1002/adma.202102595 · Cited by 298
Hao, Y.-R., Xue, H., Sun, J., Guo, N., Song, T., Sun, J., & Wang, Q. (2021) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.1c14387 · Cited by 58
Pei, Y., He, W., Wang, M., Wang, J., Sun, T., Hu, L., Zhu, J., Tan, Y., & Wang, J. (2021) · Chemical Communications · doi:10.1039/d0cc07565e · Cited by 38
Fe-doped Co-N/C as effective electrocatalyst for oxygen reaction
Lin, Q., Shang, C., Chen, Z., Akinoglu, E. M., Wang, X., & Zhou, G. (2020) · Materials Research Express · doi:10.1088/2053-1591/abaa8d · Cited by 4
Metadata
- Authors
- Liu, X., Wang, L., Yu, P., Tian, C., Sun, F., Ma, J., Li, W., & Fu, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-11-12
- Volume
- 57
- Issue
- 49
- Pages
- 16166-16170
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2897490241
- Cited by
- 469
- References
- 1
- FWCI
- 13.18
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Liu, X., Wang, L., Yu, P., Tian, C., Sun, F., Ma, J., Li, W., & Fu, H. (2018). A Stable Bifunctional Catalyst for Rechargeable Zinc–Air Batteries: Iron–Cobalt Nanoparticles Embedded in a Nitrogen‐Doped 3D Carbon Matrix. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201809009
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