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Cited by 469

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

A Stable Bifunctional Catalyst for Rechargeable Zinc–Air Batteries: Iron–Cobalt Nanoparticles Embedded in a Nitrogen‐Doped 3D Carbon Matrix

Liu, Xu, Wang, Lei, Yu, Peng, Tian, Chungui, Sun, Fanfei, Ma, Jingyuan, Li, Wei, Fu, Honggang·2018·Angewandte Chemie International Edition

Abstract

Low‐cost, efficient bifunctional electrocatalysts are needed to mediate the oxygen reduction and oxygen evolution reactions (ORR/OER) in Zn–air batteries. Such catalysts should offer binary active sites and an ability to transfer oxygen‐based species and electrons. A 3D catalyst, composed of nanoparticles of CoFe alloy embedded in N‐doped carbon nanotubes tangled with reduced graphene oxide, was developed, which presents appreciable ORR/OER activity when applied in a Zn–air battery. A high open‐circuit voltage of 1.43 V, a stable discharge voltage of 1.22 V, a high energy efficiency of 60.1 %, and excellent stability after 1 600 cycles at 10 mA cm−2 are demonstrated. An all‐solid‐state battery had an outstanding lifetime and high cell efficiency even upon bending. In situ X‐ray absorption spectroscopy revealed that OOH* and O* intermediates induce variations in the Fe−Fe and Co−Co bond lengths, respectively, suggesting that Fe and Co species are crucial to the ORR/OER processes.

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Crossref · 10.1002/anie.201809009

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Metadata

Authors
Liu, X., Wang, L., Yu, P., Tian, C., Sun, F., Ma, J., Li, W., & Fu, H.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2018-11-12
Volume
57
Issue
49
Pages
16166-16170
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2897490241
Cited by
469
References
1
FWCI
13.18
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A Stable Bifunctional Catalyst for Rechargeable Zinc–Air Batteries: Iron–Cobalt Nanoparticles Embedded in a Nitrogen‐Doped 3D Carbon Matrix. https://app.cochat.ai/papers/10.1002/anie.201809009
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Liu, X., Wang, L., Yu, P., Tian, C., Sun, F., Ma, J., Li, W., & Fu, H. (2018). A Stable Bifunctional Catalyst for Rechargeable Zinc–Air Batteries: Iron–Cobalt Nanoparticles Embedded in a Nitrogen‐Doped 3D Carbon Matrix. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201809009

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