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Dinuclear Metal Synergistic Catalysis Boosts Photochemical CO2‐to‐CO Conversion
Abstract
The solar‐driven CO 2 reduction is a challenge in the field of “artificial photosynthesis”, as most catalysts display low activity and selectivity for CO 2 reduction in water‐containing reaction systems as a result of competitive proton reduction. Herein, we report a dinuclear heterometallic complex, [CoZn(OH)L 1](ClO 4)3 (CoZn), which shows extremely high photocatalytic activity and selectivity for CO 2 reduction in water/acetonitrile solution. It achieves a selectivity of 98 % for CO 2‐to‐CO conversion, with TON and TOF values of 65000 and 1.8 s−1, respectively, 4, 19, and 45‐fold higher than the values of corresponding dinuclear homometallic [CoCo(OH)L 1](ClO 4)3 (CoCo), [ZnZn(OH)L 1](ClO 4)3 (ZnZn), and mononuclear [CoL 2(CH 3 CN)](ClO 4)2 (Co), respectively, under the same conditions. The increased photocatalytic performance of CoZn is due to the enhanced dinuclear metal synergistic catalysis (DMSC) effect between Zn II and Co II, which dramatically lowers the activation barriers of both transition states of CO 2 reduction.
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Cited by
Liu, L., & Corma, A. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00733 · Cited by 689
Boutin, E., Merakeb, L., Ma, B., Boudy, B., Wang, M., Bonin, J., Anxolabéhère-Mallart, E., & Robert, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00218f · Cited by 423
Deacy, A. C., Kilpatrick, A. F. R., Regoutz, A., & Williams, C. K. (2020) · Nature Chemistry · doi:10.1038/s41557-020-0450-3 · Cited by 325
Wang, J.-W., Jiang, L., Huang, H.-H., Han, Z., & Ouyang, G. (2021) · Nature Communications · doi:10.1038/s41467-021-24647-y · Cited by 164
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Metadata
- Authors
- Ouyang, T., Wang, H., Huang, H., Wang, J., Guo, S., Liu, W., Zhong, D., & Lu, T.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-11-14
- Volume
- 57
- Issue
- 50
- Pages
- 16480-16485
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2898406727
- Cited by
- 258
- References
- 0
- FWCI
- 4.41
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ouyang, T., Wang, H., Huang, H., Wang, J., Guo, S., Liu, W., Zhong, D., & Lu, T. (2018). Dinuclear Metal Synergistic Catalysis Boosts Photochemical CO2‐to‐CO Conversion. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201811010
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