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Puffing Up Energetic Metal–Organic Frameworks to Large Carbon Networks with Hierarchical Porosity and Atomically Dispersed Metal Sites
Abstract
Large carbon networks featuring hierarchical pores and atomically dispersed metal sites (ADMSs) are ideal materials for energy storage and conversion due to the spatially continuous conductive networks and highly active ADMSs. However, it is a challenge to synthesize such ADMS‐decorated carbon networks. Here, an innovative fusion‐foaming methodology is presented in which energetic metal–organic framework (EMOF) nanoparticles are puffed up to submillimeter‐scaled ADMS‐decorated carbon networks via a one‐step pyrolysis. Their extraordinary catalytic performance towards oxygen reduction reaction verifies the practicability of this synthetic approach. Moreover, this approach can be readily applicable to a wide range of unexplored EMOFs, expanding scopes for future materials design.
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Cites
Electrocatalyst approaches and challenges for automotive fuel cells
Debe, M. K. (2012) · Nature · doi:10.1038/nature11115 · Cited by 5,885
Atomic cobalt on nitrogen-doped graphene for hydrogen generation
Fei, H., Dong, J., Arellano-Jiménez, M. J., Ye, G., Dong Kim, N., Samuel, E. L. G., Peng, Z., Zhu, Z., Qin, F., Bao, J., et al. (2015) · Nature Communications · doi:10.1038/ncomms9668 · Cited by 1,621
Cited by
Emerging Dual‐Atomic‐Site Catalysts for Efficient Energy Catalysis
Zhang, W., Chao, Y., Zhang, W., Zhou, J., Lv, F., Wang, K., Lin, F., Luo, H., Li, J., Tong, M., et al. (2021) · Advanced Materials · doi:10.1002/adma.202102576 · Cited by 528
Recent Advances in MOF‐Derived Single Atom Catalysts for Electrochemical Applications
Song, Z., Zhang, L., Doyle‐Davis, K., Fu, X., Luo, J., & Sun, X. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001561 · Cited by 412
Hou, C., Zou, L., Wang, Y., & Xu, Q. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202011347 · Cited by 281
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Metadata
- Authors
- Zhao, R., Liang, Z., Gao, S., Yang, C., Zhu, B., Zhao, J., Qu, C., Zou, R., & Xu, Q.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-12-20
- Volume
- 58
- Issue
- 7
- Pages
- 1975-1979
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2904260516
- Cited by
- 349
- References
- 2
- FWCI
- 12.40
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhao, R., Liang, Z., Gao, S., Yang, C., Zhu, B., Zhao, J., Qu, C., Zou, R., & Xu, Q. (2019). Puffing Up Energetic Metal–Organic Frameworks to Large Carbon Networks with Hierarchical Porosity and Atomically Dispersed Metal Sites. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201811126
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