The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Effects of Intrinsic Pentagon Defects on Electrochemical Reactivity of Carbon Nanomaterials
Abstract
Theoretical calculations reveal that intrinsic pentagons in the basal plane can contribute to the local electronic redistribution and the contraction of band gap, making the carbon matrix possess superior binding affinity and electrochemical reactivity. To experimentally verify this, a pentagon‐defect‐rich carbon nanomaterial was constructed by means of in situ etching of fullerene molecules (C 60). The electrochemical tests show that, relative to hexagons, such a carbon‐based material with abundant intrinsic pentagon defects makes much greater contribution to the electrocatalytic oxygen reduction activity and electric double layer capacitance. It shows a four‐electron‐reaction mechanism similar to commercial Pt/C and other transition‐metal‐based catalysts, and a higher specific capacitance than many reported metal‐free carbon materials. These results show the influence of intrinsic pentagon defects for developing carbon‐based nanomaterials toward energy conversion and storage devices.
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Cites
Electrocatalyst approaches and challenges for automotive fuel cells
Debe, M. K. (2012) · Nature · doi:10.1038/nature11115 · Cited by 5,885
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
Shao, M., Chang, Q., Dodelet, J.-P., & Chenitz, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00462 · Cited by 3,903
Cited by
Defect Chemistry in Heterogeneous Catalysis: Recognition, Understanding, and Utilization
Xie, C., Yan, D., Li, H., Du, S., Chen, W., Wang, Y., Zou, Y., Chen, R., & Wang, S. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c03034 · Cited by 623
Defect engineering of two-dimensional materials for advanced energy conversion and storage
Liu, F., & Fan, Z. (2023) · Chemical Society Reviews · doi:10.1039/d2cs00931e · Cited by 417
Chen, D., Zhu, J., Mu, X., Cheng, R., Li, W., Liu, S., Pu, Z., Lin, C., & Mu, S. (2020) · Applied Catalysis B: Environment and Energy · doi:10.1016/j.apcatb.2020.118729 · Cited by 387
Self-citationEffect of Intrinsic Defects of Carbon Materials on the Sodium Storage Performance
Guo, R., Lv, C., Xu, W., Sun, J., Zhu, Y., Yang, X., Li, J., Sun, J., Zhang, L., & Yang, D. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903652 · Cited by 369
Zhang, C., Shen, W., Guo, K., Xiong, M., Zhang, J., & Lu, X. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c00689 · Cited by 363
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Metadata
- Authors
- Zhu, J., Huang, Y., Mei, W., Zhao, C., Zhang, C., Zhang, J., Amiinu, I. S., & Mu, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-02-14
- Volume
- 58
- Issue
- 12
- Pages
- 3859-3864
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2910019648
- Cited by
- 407
- References
- 2
- FWCI
- 9.43
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhu, J., Huang, Y., Mei, W., Zhao, C., Zhang, C., Zhang, J., Amiinu, I. S., & Mu, S. (2019). Effects of Intrinsic Pentagon Defects on Electrochemical Reactivity of Carbon Nanomaterials. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201813805
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