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Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO2 Fixation
Abstract
High‐entropy materials refer to a kind of materials in which five or more metal species were incorporated deliberately into a single lattice with random occupancy. Up to now, such a concept has been only restricted to hard materials, such as high‐entropy alloys and ceramics. Herein we report the synthesis of hybrid high‐entropy materials, polymetallic zeolitic imidazolate framework (also named as high‐entropy zeolitic imidazolate framework, HE‐ZIF), via entropy‐driven room‐temperature mechanochemistry. HE‐ZIF contains five metals including Zn II, Co II, Cd II, Ni II, and Cu II which are dispersed in the ZIF structure randomly. Moreover, HE‐ZIF shows enhanced catalytic conversion of CO 2 into carbonate compared with ZIF‐8 presumably a result of the synergistic effect of the five metal ions as Lewis acid in epoxide activation.
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Cited by
Metal–Organic Framework-Based Catalysts with Single Metal Sites
Wei, Y.-S., Zhang, M., Zou, R., & Xu, Q. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00757 · Cited by 1,233
High-entropy materials for catalysis: A new frontier
Sun, Y., & Dai, S. (2021) · Science Advances · doi:10.1126/sciadv.abg1600 · Cited by 942
Self-citationRecent progress of high-entropy materials for energy storage and conversion
Amiri, A., & Shahbazian-Yassar, R. (2021) · Journal of Materials Chemistry A · doi:10.1039/d0ta09578h · Cited by 592
High-entropy alloys in electrocatalysis: from fundamentals to applications
Ren, J.-T., Chen, L., Wang, H.-Y., & Yuan, Z.-Y. (2023) · Chemical Society Reviews · doi:10.1039/d3cs00557g · Cited by 551
High-Entropy Perovskite Fluorides: A New Platform for Oxygen Evolution Catalysis
Wang, T., Chen, H., Yang, Z., Liang, J., & Dai, S. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b12377 · Cited by 384
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Metadata
- Authors
- Xu, W., Chen, H., Jie, K., Yang, Z., Li, T., & Dai, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-03-06
- Volume
- 58
- Issue
- 15
- Pages
- 5018-5022
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2914530074
- Cited by
- 217
- References
- 0
- FWCI
- 6.57
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xu, W., Chen, H., Jie, K., Yang, Z., Li, T., & Dai, S. (2019). Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO2 Fixation. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201900787
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