The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Designed Synthesis of a 2D Porphyrin‐Based sp2Carbon‐Conjugated Covalent Organic Framework for Heterogeneous Photocatalysis
Abstract
The construction of stable covalent organic frameworks (COFs) for various applications is highly desirable. Herein, we report the synthesis of a novel two‐dimensional (2D) porphyrin‐based sp 2 carbon‐conjugated COF (Por‐sp 2 c‐COF), which adopts an eclipsed AA stacking structure with a Brunauer—Emmett—Teller surface area of 689 m 2 g−1. Owing to the C=C linkages, Por‐sp 2 c‐COF shows a high chemical stability under various conditions, even under harsh conditions such as 9 m HCl and 9 m NaOH solutions. Interestingly, Por‐sp 2 c‐COF can be used as a metal‐free heterogeneous photocatalyst for the visible‐light‐induced aerobic oxidation of amines to imines. More importantly, in comparison to imine‐linked Por‐COF, the inherent structure of Por‐sp 2 c‐COF equips it with several advantages as a photocatalyst, including reusability and high photocatalytic performance. This clearly demonstrates that sp 2 carbon‐linked 2D COFs can provide an interesting platform for heterogeneous photocatalysis.
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Cites
Porphyrins as excellent dyes for dye-sensitized solar cells: recent developments and insights
Higashino, T., & Imahori, H. (2015) · Dalton Transactions · doi:10.1039/c4dt02756f · Cited by 582
Cited by
Covalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Metadata
- Authors
- Chen, R., Shi, J., Ma, Y., Lin, G., Lang, X., & Wang, C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-04-04
- Volume
- 58
- Issue
- 19
- Pages
- 6430-6434
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2923917422
- Cited by
- 697
- References
- 1
- FWCI
- 30.65
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, R., Shi, J., Ma, Y., Lin, G., Lang, X., & Wang, C. (2019). Designed Synthesis of a 2D Porphyrin‐Based sp2Carbon‐Conjugated Covalent Organic Framework for Heterogeneous Photocatalysis. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201902543
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