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Cited by 264

The DOI matches its Crossref record; 20 of the 20 references it cites were found in a registry or an index.

Hybrid Chloroantimonates(III): Thermally Induced Triple‐Mode Reversible Luminescent Switching and Laser‐Printable Rewritable Luminescent Paper

Wang, Zeping, Zhang, Zhizhuan, Tao, Luqi, Shen, Nannan, Hu, Bing, Gong, Liaokuo, Li, Jianrong, Chen, Xianping, Huang, Xiaoying·2019·Angewandte Chemie International Edition

Abstract

Two hybrid chloroantimonates(III), [Bzmim]3 SbCl 6 (1, Bzmim=1‐benzyl‐3‐methylimidazolium, T m1=410 K) and [Bzmim]2 SbCl 5 (2, T m2=348 K) are presented. 1 exhibits green emission (quantum efficiency of 87.5 %); 2 exhibits blue and red emissions under the irradiation of 310 and 396 nm light, respectively. Using different cooling methods, crystalline 1 and IL@2 (IL=ionic liquid of [Bzmim]Cl) could be generated from the molten 1. Reversible structural and PL transformation triggered by moisture or heat was observed between 1 and IL@2. Such PL switching, combined with the crystallization‐induced PL properties of 1 and 2, resulted in the firstly reported triple‐mode reversible PL switching, that is, on–off (T>T m1), color switching (T<T m2), and on–off–on (T m2<T<T m1). Furthermore, ink‐ and mask‐free laser‐printable rewritable PL paper was achieved. This study demonstrates the promise of dynamic insertion/extraction of ILs in hybrid chloroantimonates for anti‐counterfeiting and rewritable PL paper.

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Metadata

Authors
Wang, Z., Zhang, Z., Tao, L., Shen, N., Hu, B., Gong, L., Li, J., Chen, X., & Huang, X.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2019-06-05
Volume
58
Issue
29
Pages
9974-9978
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2944243407
Cited by
264
References
20
FWCI
10.05
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Hybrid Chloroantimonates(III): Thermally Induced Triple‐Mode Reversible Luminescent Switching and Laser‐Printable Rewritable Luminescent Paper. https://app.cochat.ai/papers/10.1002/anie.201903945
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Wang, Z., Zhang, Z., Tao, L., Shen, N., Hu, B., Gong, L., Li, J., Chen, X., & Huang, X. (2019). Hybrid Chloroantimonates(III): Thermally Induced Triple‐Mode Reversible Luminescent Switching and Laser‐Printable Rewritable Luminescent Paper. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201903945

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