The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Isolated Square‐Planar Copper Center in Boron Imidazolate Nanocages for Photocatalytic Reduction of CO2 to CO
Abstract
Photocatalytic reduction of CO 2 to value‐added fuel has been considered to be a promising strategy to reduce global warming and shortage of energy. Rational design and synthesis of catalysts to maximumly expose the active sites is the key to activate CO 2 molecules and determine the reaction selectivity. Herein, we synthesize a well‐defined copper‐based boron imidazolate cage (BIF‐29) with six exposed mononuclear copper centers for the photocatalytic reduction of CO 2. Theoretical calculations show a single Cu site including weak coordinated water delivers a new state in the conduction band near the Fermi level and stabilizes the *COOH intermediate. Steady‐state and time‐resolved fluorescence spectra show these Cu sites promote the separation of electron–hole pairs and electron transfer. As a result, the cage achieves solar‐driven reduction of CO 2 to CO with an evolution rate of 3334 μmol g−1 h−1 and a high selectivity of 82.6 %.
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Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
Yang, H. B., Hung, S.-F., Liu, S., Yuan, K., Miao, S., Zhang, L., Huang, X., Wang, H.-Y., Cai, W., Chen, R., et al. (2018) · Nature Energy · doi:10.1038/s41560-017-0078-8 · Cited by 2,239
Self-citationThe Fischer-Tropsch process: 1950-2000
Dry, M. E. (2002) · Catalysis Today · doi:10.1016/s0920-5861(01)00453-9 · Cited by 2,061
Xu, H.-Q., Hu, J., Wang, D., Li, Z., Zhang, Q., Luo, Y., Yu, S.-H., & Jiang, H.-L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08773 · Cited by 1,166
Cited by
Sheng, J., He, Y., Li, J., Yuan, C., Huang, H., Wang, S., Sun, Y., Wang, Z., & Dong, F. (2020) · ACS Nano · doi:10.1021/acsnano.0c04659 · Cited by 522
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Metadata
- Authors
- Zhang, H., Hong, Q., Li, J., Wang, F., Huang, X., Chen, S., Tu, W., Yu, D., Xu, R., Zhou, T., & Zhang, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-07-18
- Volume
- 58
- Issue
- 34
- Pages
- 11752-11756
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2951695797
- Cited by
- 249
- References
- 3
- FWCI
- 6.85
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, H., Hong, Q., Li, J., Wang, F., Huang, X., Chen, S., Tu, W., Yu, D., Xu, R., Zhou, T., & Zhang, J. (2019). Isolated Square‐Planar Copper Center in Boron Imidazolate Nanocages for Photocatalytic Reduction of CO2 to CO. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201905869
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