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Cited by 341

The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.

Vinylene‐Linked Covalent Organic Frameworks by Base‐Catalyzed Aldol Condensation

Open access
Acharjya, Amitava, Pachfule, Pradip, Roeser, Jérôme, Schmitt, Franz‐Josef, Thomas, Arne·2019·Angewandte Chemie International Edition

Abstract

Two 2D covalent organic frameworks (COFs) linked by vinylene (−CH=CH−) groups (V‐COF‐1 and V‐COF‐2) are synthesized by exploiting the electron deficient nature of the aromatic s‐triazine unit of C 3‐symmetric 2,4,6‐trimethyl‐s‐triazine (TMT). The acidic terminal methyl hydrogens of TMT can easily be abstracted by a base, resulting in a stabilized carbanion, which further undergoes aldol condensation with multitopic aryl aldehydes to be reticulated into extended crystalline frameworks (V‐COFs). Both V‐COF‐1 (with terepthalaldehyde (TA)) and V‐COF‐2 (with 1,3,5‐tris(p‐formylphenyl)benzene (TFPB)) are polycrystalline and exhibit permanent porosity and BET surface areas of 1341 m 2 g−1 and 627 m 2 g−1, respectively. Owing to the close proximity (3.52 Å) of the pre‐organized vinylene linkages within adjacent 2D layers stacked in eclipsed fashion, [2+2] photo‐cycloadditon in V‐COF‐1 formed covalent crosslinks between the COF layers.

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Metadata

Authors
Acharjya, A., Pachfule, P., Roeser, J., Schmitt, F., & Thomas, A.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2019-09-09
Volume
58
Issue
42
Pages
14865-14870
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2962763311
Cited by
341
References
47
FWCI
11.81
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Vinylene‐Linked Covalent Organic Frameworks by Base‐Catalyzed Aldol Condensation. https://app.cochat.ai/papers/10.1002/anie.201905886
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Acharjya, A., Pachfule, P., Roeser, J., Schmitt, F., & Thomas, A. (2019). Vinylene‐Linked Covalent Organic Frameworks by Base‐Catalyzed Aldol Condensation. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201905886

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