The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.
Vinylene‐Linked Covalent Organic Frameworks by Base‐Catalyzed Aldol Condensation
Open accessAbstract
Two 2D covalent organic frameworks (COFs) linked by vinylene (−CH=CH−) groups (V‐COF‐1 and V‐COF‐2) are synthesized by exploiting the electron deficient nature of the aromatic s‐triazine unit of C 3‐symmetric 2,4,6‐trimethyl‐s‐triazine (TMT). The acidic terminal methyl hydrogens of TMT can easily be abstracted by a base, resulting in a stabilized carbanion, which further undergoes aldol condensation with multitopic aryl aldehydes to be reticulated into extended crystalline frameworks (V‐COFs). Both V‐COF‐1 (with terepthalaldehyde (TA)) and V‐COF‐2 (with 1,3,5‐tris(p‐formylphenyl)benzene (TFPB)) are polycrystalline and exhibit permanent porosity and BET surface areas of 1341 m 2 g−1 and 627 m 2 g−1, respectively. Owing to the close proximity (3.52 Å) of the pre‐organized vinylene linkages within adjacent 2D layers stacked in eclipsed fashion, [2+2] photo‐cycloadditon in V‐COF‐1 formed covalent crosslinks between the COF layers.
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Cites
Porous, Crystalline, Covalent Organic Frameworks
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Structural absorption by barbule microstructures of super black bird of paradise feathers
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The atom, the molecule, and the covalent organic framework
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Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
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Self-citationDesigned Synthesis of 3D Covalent Organic Frameworks
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Photodimerization in the solid state
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Cited by
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Yang, J., Ghosh, S., Roeser, J., Acharjya, A., Penschke, C., Tsutsui, Y., Rabeah, J., Wang, T., Djoko Tameu, S. Y., Ye, M.-Y., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-33875-9 · Cited by 279
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Metadata
- Authors
- Acharjya, A., Pachfule, P., Roeser, J., Schmitt, F., & Thomas, A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-09-09
- Volume
- 58
- Issue
- 42
- Pages
- 14865-14870
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2962763311
- Cited by
- 341
- References
- 47
- FWCI
- 11.81
- Type
- journal article
- Language
- en
- Open access
- hybrid
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