The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Negative Charging of Transition‐Metal Phosphides via Strong Electronic Coupling for Destabilization of Alkaline Water
Abstract
Heterogeneous electrocatalysis typically involves charge transfer between surface active sites and adsorbed species. Therefore, modulating the surface charge state of an electrocatalyst can be used to enhance performance. A series of negatively charged transition‐metal (Fe, Co, Ni, Cu,and NiCo) phosphides were fabricated by designing strong electronic coupling with hydr(oxy)oxides formed in situ. Physicochemical characterizations, together with DFT computations, demonstrate that strong electronic coupling renders transition‐metal phosphides negatively charged. This facilitates destabilization of alkaline water adsorption and dissociation to result in significantly improved H 2 evolution. Negatively charged Ni 2 P/nickel hydr(oxy)oxide for example exhibits a significantly low overpotential of 138 mV at 100 mA cm−2, superior to that without strong electronic coupling and also commercial Pt/C.
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Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
Subbaraman, R., Tripkovic, D., Strmcnik, D., Chang, K.-C., Uchimura, M., Paulikas, A. P., Stamenkovic, V., & Markovic, N. M. (2011) · Science · doi:10.1126/science.1211934 · Cited by 3,135
An efficient and pH-universal ruthenium-based catalyst for the hydrogen evolution reaction
Mahmood, J., Li, F., Jung, S.-M., Okyay, M. S., Ahmad, I., Kim, S.-J., Park, N., Jeong, H. Y., & Baek, J.-B. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2016.304 · Cited by 1,685
Jiao, Y., Zheng, Y., Davey, K., & Qiao, S.-Z. (2016) · Nature Energy · doi:10.1038/nenergy.2016.130 · Cited by 1,196
Self-citationKibsgaard, J., & Jaramillo, T. F. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408222 · Cited by 1,048
Anchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution
Xue, Y., Huang, B., Yi, Y., Guo, Y., Zuo, Z., Li, Y., Jia, Z., Liu, H., & Li, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03896-4 · Cited by 1,011
Voiry, D., Fullon, R., Yang, J., de Carvalho Castro e Silva, C., Kappera, R., Bozkurt, I., Kaplan, D., Lagos, M. J., Batson, P. E., Gupta, G., et al. (2016) · Nature Materials · doi:10.1038/nmat4660 · Cited by 824
You, B., Liu, X., Hu, G., Gul, S., Yano, J., Jiang, D.-E., & Sun, Y. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06434 · Cited by 266
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Li, Y., Dong, Z., & Jiao, L. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902104 · Cited by 603
Fu, H. Q., Zhou, M., Liu, P. F., Liu, P., Yin, H., Sun, K. Z., Yang, H. G., Al-Mamun, M., Hu, P., Wang, H.-F., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c01094 · Cited by 508
Shi, Y., Li, M., Yu, Y., & Zhang, B. (2020) · Energy & Environmental Science · doi:10.1039/d0ee02577a · Cited by 426
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Zhu, Q., Xu, Z., Qiu, B., Xing, M., & Zhang, J. (2021) · Small · doi:10.1002/smll.202101070 · Cited by 380
Weng, C., Ren, J., & Yuan, Z. (2020) · ChemSusChem · doi:10.1002/cssc.202000416 · Cited by 342
Metadata
- Authors
- You, B., Zhang, Y., Jiao, Y., Davey, K., & Qiao, S. Z.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-07-12
- Volume
- 58
- Issue
- 34
- Pages
- 11796-11800
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2951661513
- Cited by
- 207
- References
- 9
- FWCI
- 6.54
- Type
- journal article
- Language
- en
- Open access
- closed
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