The DOI matches its Crossref record.
Switching on the Photocatalysis of Metal–Organic Frameworks by Engineering Structural Defects
Abstract
Defect engineering is a versatile approach to modulate band and electronic structures as well as materials performance. Herein, metal–organic frameworks (MOFs) featuring controlled structural defects, namely UiO‐66‐NH 2‐X (X represents the molar equivalents of the modulator, acetic acid, with respect to the linker in synthesis), were synthesized to systematically investigate the effect of structural defects on photocatalytic properties. Remarkably, structural defects in MOFs are able to switch on the photocatalysis. The photocatalytic H 2 production rate presents a volcano‐type trend with increasing structural defects, where Pt@UiO‐66‐NH 2‐100 exhibits the highest activity. Ultrafast transient absorption spectroscopy unveils that UiO‐66‐NH 2‐100 with moderate structural defects possesses the fastest relaxation kinetics and the highest charge separation efficiency, while excessive defects retard the relaxation and reduce charge separation efficiency.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Ma, X., Liu, H., Yang, W., Mao, G., Zheng, L., & Jiang, H.-L. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05032 · Cited by 445
Self-citationXiang, W., Zhang, Y., Chen, Y., Liu, C.-J., & Tu, X. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta08009h · Cited by 359
Hu, H., Li, X., Zhang, K., Yan, G., Kong, W., Qin, A., Ma, Y., Li, A., Wang, K., Huang, H., et al. (2025) · Advanced Materials · doi:10.1002/adma.202419023 · Cited by 122
Metadata
- Authors
- Ma, X., Wang, L., Zhang, Q., & Jiang, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-08-02
- Volume
- 58
- Issue
- 35
- Pages
- 12175-12179
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2953401462
- Cited by
- 542
- References
- 0
- FWCI
- 20.71
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Switching on the Photocatalysis of Metal–Organic Frameworks by Engineering Structural Defects. https://app.cochat.ai/papers/10.1002/anie.201907074
- The paper
- Ma, X., Wang, L., Zhang, Q., & Jiang, H. (2019). Switching on the Photocatalysis of Metal–Organic Frameworks by Engineering Structural Defects. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201907074
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
