The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Reordering d Orbital Energies of Single‐Site Catalysts for CO2 Electroreduction
Open accessAbstract
The single‐site catalyst (SSC) characteristic of atomically dispersed active centers will not only maximize the catalytic activity, but also provide a promising platform for establishing the structure–activity relationship. However, arbitrary arrangements of active sites in the existed SSCs make it difficult for mechanism understanding and performance optimization. Now, a well‐defined ultrathin SSC is fabricated by assembly of metal‐porphyrin molecules, which enables the precise identification of the active sites for d‐orbital energy engineering. The activity of as‐assembled products for electrocatalytic CO 2 reduction is significantly promoted via lifting up the energy level of metal d orbitals, exhibiting a remarkable Faradaic efficiency of 96 % at the overpotential of 500 mV. Furthermore, a turnover frequency of 4.21 s−1 is achieved with negligible decay over 48 h.
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Cites
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
Yang, H. B., Hung, S.-F., Liu, S., Yuan, K., Miao, S., Zhang, L., Huang, X., Wang, H.-Y., Cai, W., Chen, R., et al. (2018) · Nature Energy · doi:10.1038/s41560-017-0078-8 · Cited by 2,239
Self-citationEnhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Jiang, K., Siahrostami, S., Akey, A. J., Li, Y., Lu, Z., Lattimer, J., Hu, Y., Stokes, C., Gangishetty, M., Chen, G., et al. (2017) · Chem · doi:10.1016/j.chempr.2017.09.014 · Cited by 406
Cited by
Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts
Sun, L., Reddu, V., Fisher, A. C., & Wang, X. (2020) · Energy & Environmental Science · doi:10.1039/c9ee03660a · Cited by 452
Jiao, L., Yang, W., Wan, G., Zhang, R., Zheng, X., Zhou, H., Yu, S., & Jiang, H. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202008787 · Cited by 412
Metadata
- Authors
- Han, J., An, P., Liu, S., Zhang, X., Wang, D., Yuan, Y., Guo, J., Qiu, X., Hou, K., Shi, L., Zhang, Y., Zhao, S., Long, C., & Tang, Z.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-08-07
- Volume
- 58
- Issue
- 36
- Pages
- 12711-12716
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2958375957
- Cited by
- 235
- References
- 3
- FWCI
- 6.80
- Type
- journal article
- Language
- en
- Open access
- green
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- Han, J., An, P., Liu, S., Zhang, X., Wang, D., Yuan, Y., Guo, J., Qiu, X., Hou, K., Shi, L., Zhang, Y., Zhao, S., Long, C., & Tang, Z. (2019). Reordering d Orbital Energies of Single‐Site Catalysts for CO2 Electroreduction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201907399
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