The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.
AIE Triggers the Circularly Polarized Luminescence of Atomically Precise Enantiomeric Copper(I) Alkynyl Clusters
Abstract
Atomically precise enantiomeric metal clusters are scarce, and copper(I) alkynyl clusters with intense circularly polarized luminescence (CPL) responses have not been reported. A pair of chiral alkynyl ligands, (R/S)‐2‐diphenyl‐2‐hydroxylmethylpyrrolidine‐1‐propyne (abbreviated as R/S‐DPM) we successfully prepared and single crystals were characterized of optically pure enantiomeric pair of atomically‐precise copper(I) clusters, [Cu 14(R/S‐DPM)8](PF 6)6(denoted as R/S‐Cu 14), which feature bright red luminescence and CPL with a high luminescence anisotropy factor (glum). A dilute solution containing R/S‐Cu 14was nonluminescent and CPL inactive at room temperature. Crystallization‐ and aggregation‐induced emission (CIE and AIE, respectively) contribute to the triggering of the CPL of R/S‐Cu 14in the crystalline and aggregated states. Their AIE behavior and good biocompatibility indicated applications of these copper(I) clusters in cell imaging in HeLa and NG108‐15 cells.
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Aggregation-Induced Emission: Together We Shine, United We Soar!
Mei, J., Leung, N. L. C., Kwok, R. T. K., Lam, J. W. Y., & Tang, B. Z. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00263 · Cited by 8,270
Hong, Y., Lam, J. W. Y., & Tang, B. Z. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15113d · Cited by 6,363
Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities
Jin, R., Zeng, C., Zhou, M., & Chen, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00703 · Cited by 3,459
Atomically Precise Clusters of Noble Metals: Emerging Link between Atoms and Nanoparticles
Chakraborty, I., & Pradeep, T. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00769 · Cited by 2,501
Luo, Z., Yuan, X., Yu, Y., Zhang, Q., Leong, D. T., Lee, J. Y., & Xie, J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja306199p · Cited by 1,681
Light-Emitting Self-Assembled Materials Based on d8 and d10 Transition Metal Complexes
Yam, V. W.-W., Au, V. K.-M., & Leung, S. Y.-L. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00074 · Cited by 1,661
Tailoring the photoluminescence of atomically precise nanoclusters
Kang, X., & Zhu, M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00800k · Cited by 1,065
Huang, R.-W., Wei, Y.-S., Dong, X.-Y., Wu, X.-H., Du, C.-X., Zang, S.-Q., & Mak, T. C. W. (2017) · Nature Chemistry · doi:10.1038/nchem.2718 · Cited by 1,001
Self-citationChiral Inorganic Nanostructures
Ma, W., Xu, L., de Moura, A. F., Wu, X., Kuang, H., Xu, C., & Kotov, N. A. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00755 · Cited by 994
Luminescent Metal Nanoclusters with Aggregation-Induced Emission
Goswami, N., Yao, Q., Luo, Z., Li, J., Chen, T., & Xie, J. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b02765 · Cited by 716
Cited by
Gong, Z.-L., Zhu, X., Zhou, Z., Zhang, S.-W., Yang, D., Zhao, B., Zhang, Y.-P., Deng, J., Cheng, Y., Zheng, Y.-X., et al. (2021) · Science China Chemistry · doi:10.1007/s11426-021-1146-6 · Cited by 608
Self-citationLiquid Crystal Assembly for Ultra-dissymmetric Circularly Polarized Luminescence and Beyond
Wu, Y., Li, M., Zheng, Z.-G., Yu, Z.-Q., & Zhu, W.-H. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c01122 · Cited by 281
Chemical Flexibility of Atomically Precise Metal Clusters
Li, S., Li, N.-N., Dong, X.-Y., Zang, S.-Q., & Mak, T. C. W. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00896 · Cited by 280
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Metadata
- Authors
- Zhang, M., Dong, X., Wang, Z., Li, H., Li, S., Zhao, X., & Zang, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-09-18
- Volume
- 59
- Issue
- 25
- Pages
- 10052-10058
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2970704366
- Cited by
- 285
- References
- 37
- FWCI
- 10.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, M., Dong, X., Wang, Z., Li, H., Li, S., Zhao, X., & Zang, S. (2020). AIE Triggers the Circularly Polarized Luminescence of Atomically Precise Enantiomeric Copper(I) Alkynyl Clusters. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201908909
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