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Photostimulus‐Responsive Large‐Area Two‐Dimensional Covalent Organic Framework Films

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Yu, Fei, Liu, Wenbo, Li, Bang, Tian, Dan, Zuo, Jing‐Lin, Zhang, Qichun·2019·Angewandte Chemie International Edition

Abstract

Using an external stimulus to modulate the electronic structure of covalent organic frameworks (COFs) is very important because such a response will endow them with additional functions. A two‐dimensional (2D) COF, constructed from a photo‐responsive unit (1,2‐bis(5‐formyl‐2‐methylthien‐3‐yl)cyclopentene), can reversibly switch its electrical conductivity 200 times from low state (the open form) to high state (the closed form) upon irradiation with UV light and reversible with visible light. This reversible phenomenon can be monitored through a circuit containing a light‐emitting diode (LED). Photoinduced ring‐closing/opening reactions do not destroy the integrity of the frameworks, and both processes follow logarithmic carrier generation with time. Moreover, the correlation between COFs electronic properties and changes in photoinduced kinetics and absorption curves has been demonstrated.

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Metadata

Authors
Yu, F., Liu, W., Li, B., Tian, D., Zuo, J., & Zhang, Q.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2019-09-20
Volume
58
Issue
45
Pages
16101-16104
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2971742449
Cited by
195
References
0
FWCI
9.64
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Photostimulus‐Responsive Large‐Area Two‐Dimensional Covalent Organic Framework Films. https://app.cochat.ai/papers/10.1002/anie.201909613
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Yu, F., Liu, W., Li, B., Tian, D., Zuo, J., & Zhang, Q. (2019). Photostimulus‐Responsive Large‐Area Two‐Dimensional Covalent Organic Framework Films. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201909613

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