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Photostimulus‐Responsive Large‐Area Two‐Dimensional Covalent Organic Framework Films
Open accessAbstract
Using an external stimulus to modulate the electronic structure of covalent organic frameworks (COFs) is very important because such a response will endow them with additional functions. A two‐dimensional (2D) COF, constructed from a photo‐responsive unit (1,2‐bis(5‐formyl‐2‐methylthien‐3‐yl)cyclopentene), can reversibly switch its electrical conductivity 200 times from low state (the open form) to high state (the closed form) upon irradiation with UV light and reversible with visible light. This reversible phenomenon can be monitored through a circuit containing a light‐emitting diode (LED). Photoinduced ring‐closing/opening reactions do not destroy the integrity of the frameworks, and both processes follow logarithmic carrier generation with time. Moreover, the correlation between COFs electronic properties and changes in photoinduced kinetics and absorption curves has been demonstrated.
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Cited by
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Li, D., Yang, Y., Yang, J., Fang, M., Tang, B. Z., & Li, Z. (2022) · Nature Communications · doi:10.1038/s41467-022-28011-6 · Cited by 528
Recent Progress in Stimulus-Responsive Two-Dimensional Metal–Organic Frameworks
Li, C., Wang, K., Li, J., & Zhang, Q. (2020) · ACS Materials Letters · doi:10.1021/acsmaterialslett.0c00148 · Cited by 252
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Metadata
- Authors
- Yu, F., Liu, W., Li, B., Tian, D., Zuo, J., & Zhang, Q.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-09-20
- Volume
- 58
- Issue
- 45
- Pages
- 16101-16104
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2971742449
- Cited by
- 195
- References
- 0
- FWCI
- 9.64
- Type
- journal article
- Language
- en
- Open access
- green
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- Yu, F., Liu, W., Li, B., Tian, D., Zuo, J., & Zhang, Q. (2019). Photostimulus‐Responsive Large‐Area Two‐Dimensional Covalent Organic Framework Films. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201909613
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