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Cited by 182

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Amorphous Ionic Polymers with Color‐Tunable Ultralong Organic Phosphorescence

Wang, He, Shi, Huifang, Ye, Wenpeng, Yao, Xiaokang, Wang, Qian, Dong, Chaomin, Jia, Wenyong, Ma, Huili, Cai, Suzhi, Huang, Kaiwei, Fu, Lishun, Zhang, Yanyun, Zhi, Jiahuan, Gu, Long, Zhao, Yanli, An, Zhongfu, Huang, Wei·2019·Angewandte Chemie International Edition

Abstract

Amorphous purely organic phosphorescence materials with long‐lived and color‐tunable emission are rare. Herein, we report a concise chemical ionization strategy to endow conventional poly(4‐vinylpyridine) (PVP) derivatives with ultralong organic phosphorescence (UOP) under ambient conditions. After the ionization of 1,4‐butanesultone, the resulting PVP‐S phosphor showed a UOP lifetime of 578.36 ms, which is 525 times longer than that of PVP polymer itself. Remarkably, multicolor UOP emission ranging from blue to red was observed with variation of the excitation wavelength, which has rarely been reported for organic luminescent materials. This finding not only provides a guideline for developing amorphous polymers with UOP properties, but also extends the scope of room‐temperature phosphorescence (RTP) materials for practical applications in photoelectric fields.

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Metadata

Authors
Wang, H., Shi, H., Ye, W., Yao, X., Wang, Q., Dong, C., Jia, W., Ma, H., Cai, S., Huang, K., Fu, L., Zhang, Y., Zhi, J., Gu, L., Zhao, Y., An, Z., & Huang, W.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2019-11-27
Volume
58
Issue
52
Pages
18776-18782
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2982183440
Cited by
182
References
1
FWCI
8.08
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Amorphous Ionic Polymers with Color‐Tunable Ultralong Organic Phosphorescence. https://app.cochat.ai/papers/10.1002/anie.201911331
The paper
Wang, H., Shi, H., Ye, W., Yao, X., Wang, Q., Dong, C., Jia, W., Ma, H., Cai, S., Huang, K., Fu, L., Zhang, Y., Zhi, J., Gu, L., Zhao, Y., An, Z., & Huang, W. (2019). Amorphous Ionic Polymers with Color‐Tunable Ultralong Organic Phosphorescence. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201911331

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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