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Cited by 243

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Towards Long‐Term Photostability of Nickel Hydroxide/BiVO4 Photoanodes for Oxygen Evolution Catalysts via In Situ Catalyst Tuning

Gao, Rui‐Ting, He, Dan, Wu, Lijun, Hu, Kan, Liu, Xianhu, Su, Yiguo, Wang, Lei·2020·Angewandte Chemie International Edition

Abstract

Increasing long‐term photostability of BiVO 4 photoelectrode is an important issue for solar water splitting. The NiOOH oxygen evolution catalyst (OEC) has fast water oxidation kinetics compared to the FeOOH OEC. However, it generally shows a lower photoresponse and poor stability because of the more substantial interface recombination at the NiOOH/BiVO 4 junction. Herein, we utilize a plasma etching approach to reduce both interface/surface recombination at NiOOH/BiVO 4 and NiOOH/electrolyte junctions. Further, adding Fe 2+ into the borate buffer electrolyte alleviates the active but unstable character of etched‐NiOOH/BiVO 4, leading to an outstanding oxygen evolution over 200 h. The improved charge transfer and photostability can be attributed to the active defects and a mixture of NiOOH/NiO/Ni in OEC induced by plasma etching. Metallic Ni acts as the ion source for the in situ generation of the NiFe OEC over long‐term durability.

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Metadata

Authors
Gao, R., He, D., Wu, L., Hu, K., Liu, X., Su, Y., & Wang, L.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2020-02-12
Volume
59
Issue
15
Pages
6213-6218
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W3005850237
Cited by
243
References
1
FWCI
7.85
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Towards Long‐Term Photostability of Nickel Hydroxide/BiVO4 Photoanodes for Oxygen Evolution Catalysts via In Situ Catalyst Tuning. https://app.cochat.ai/papers/10.1002/anie.201915671
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Gao, R., He, D., Wu, L., Hu, K., Liu, X., Su, Y., & Wang, L. (2020). Towards Long‐Term Photostability of Nickel Hydroxide/BiVO4 Photoanodes for Oxygen Evolution Catalysts via In Situ Catalyst Tuning. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201915671

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