The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.
Silver Single Atom in Carbon Nitride Catalyst for Highly Efficient Photocatalytic Hydrogen Evolution
Abstract
Single atom catalysts (SACs) with the maximized metal atom efficiency have sparked great attention. However, it is challenging to obtain SACs with high metal loading, high catalytic activity, and good stability. Herein, we demonstrate a new strategy to develop a highly active and stable Ag single atom in carbon nitride (Ag‐N 2 C 2/CN) catalyst with a unique coordination. The Ag atomic dispersion and Ag‐N 2 C 2 configuration have been identified by aberration‐correction high‐angle‐annular‐dark‐field scanning transmission electron microscopy (AC‐HAADF‐STEM) and extended X‐ray absorption. Experiments and DFT calculations further verify that Ag‐N 2 C 2 can reduce the H 2 evolution barrier, expand the light absorption range, and improve the charge transfer of CN. As a result, the Ag‐N 2 C 2/CN catalyst exhibits much better H 2 evolution activity than the N‐coordinated Ag single atom in CN (Ag‐N 4/CN), and is even superior to the Pt nanoparticle‐loaded CN (Pt NP/CN). This work provides a new idea for the design and synthesis of SACs with novel configurations and excellent catalytic activity and durability.
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Cites
Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms
Zhang, L., Zhou, M., Wang, A., & Zhang, T. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00230 · Cited by 1,611
Self-citationAtomically dispersed Fe 3+ sites catalyze efficient CO 2 electroreduction to CO
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Direct transformation of bulk copper into copper single sites via emitting and trapping of atoms
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Light-driven methane dry reforming with single atomic site antenna-reactor plasmonic photocatalysts
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Multicomponent electrocatalyst with ultralow Pt loading and high hydrogen evolution activity
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Atomically dispersed iron hydroxide anchored on Pt for preferential oxidation of CO in H2
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Single-atom Rh/N-doped carbon electrocatalyst for formic acid oxidation
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Cited by
Zhang, Y., Zhao, J., Wang, H., Xiao, B., Zhang, W., Zhao, X., Lv, T., Thangamuthu, M., Zhang, J., Guo, Y., et al. (2022) · Nature Communications · doi:10.1038/s41467-021-27698-3 · Cited by 490
Zhang, S., Zhang, Z., Si, Y., Li, B., Deng, F., Yang, L., Liu, X., Dai, W., & Luo, S. (2021) · ACS Nano · doi:10.1021/acsnano.1c05834 · Cited by 394
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Metadata
- Authors
- Jiang, X., Zhang, L., Liu, H., Wu, D., Wu, F., Tian, L., Liu, L., Zou, J., Luo, S., & Chen, B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-10-13
- Volume
- 59
- Issue
- 51
- Pages
- 23112-23116
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3084200785
- Cited by
- 432
- References
- 42
- FWCI
- 12.05
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jiang, X., Zhang, L., Liu, H., Wu, D., Wu, F., Tian, L., Liu, L., Zou, J., Luo, S., & Chen, B. (2020). Silver Single Atom in Carbon Nitride Catalyst for Highly Efficient Photocatalytic Hydrogen Evolution. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202011495
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