The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
Thiazolo[5,4‐d]thiazole‐Based Donor–Acceptor Covalent Organic Framework for Sunlight‐Driven Hydrogen Evolution
Abstract
2D covalent organic frameworks (COFs) could have well‐defined arrangements of photo‐ and electro‐active units that serve as electron or hole transport channels for solar energy harvesting and conversion, but their insufficient charge transfer and rapid charge recombination impede the sunlight‐driven photocatalytic performance. We report a new donor–acceptor (D–A) system, PyTz‐COF that was constructed from the electron‐rich pyrene (Py) and electron‐deficient thiazolo[5,4‐d]thiazole (Tz). With its bicontinuous heterojunction, PyTz‐COF demonstrated exceptional optoelectronic properties, photocatalytic ability in superoxide anion radical‐mediated coupling of (arylmethyl)amines and photoelectrochemical activity in sunlight‐driven hydrogen evolution. Remarkably, PyTz‐COF exhibited a photocurrent up to 100 μA cm−2 at 0.2 V vs. RHE and could reach a hydrogen evolution rate of 2072.4 μmol g−1 h−1. This work is paving the way for reticular design of highly efficient and highly active D–A systems for solar energy harvesting and conversion.
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Cited by
Qian, Y., Han, Y., Zhang, X., Yang, G., Zhang, G., & Jiang, H.-L. (2023) · Nature Communications · doi:10.1038/s41467-023-38884-w · Cited by 448
Liu, S., Wang, M., He, Y., Cheng, Q., Qian, T., & Yan, C. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214882 · Cited by 236
Li, W., Wang, F., Chu, X.-S., Dang, Y.-Y., Liu, X.-Y., Ma, T., Li, J.-Y., & Wang, C.-Y. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.132441 · Cited by 38
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Metadata
- Authors
- Li, W., Huang, X., Zeng, T., Liu, Y. A., Hu, W., Yang, H., Zhang, Y., & Wen, K.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-12-29
- Volume
- 60
- Issue
- 4
- Pages
- 1869-1874
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3111219899
- Cited by
- 355
- References
- 48
- FWCI
- 16.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, W., Huang, X., Zeng, T., Liu, Y. A., Hu, W., Yang, H., Zhang, Y., & Wen, K. (2021). Thiazolo[5,4‐d]thiazole‐Based Donor–Acceptor Covalent Organic Framework for Sunlight‐Driven Hydrogen Evolution. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202014408
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