The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.
Altering Hydrogenation Pathways in Photocatalytic Nitrogen Fixation by Tuning Local Electronic Structure of Oxygen Vacancy with Dopant
Abstract
To avoid the energy‐consuming step of direct N≡N bond cleavage, photocatalytic N 2 fixation undergoing the associative pathways has been developed for mild‐condition operation. However, it is a fundamental yet challenging task to gain comprehensive understanding on how the associative pathways (i.e., alternating vs. distal) are influenced and altered by the fine structure of catalysts, which eventually holds the key to significantly promote the practical implementation. Herein, we introduce Fe dopants into TiO 2 nanofibers to stabilize oxygen vacancies and simultaneously tune their local electronic structure. The combination of in situ characterizations with first‐principles simulations reveals that the modulation of local electronic structure by Fe dopants turns the hydrogenation of N 2 from associative alternating pathway to associative distal pathway. This work provides fresh hints for rationally controlling the reaction pathways toward efficient photocatalytic nitrogen fixation.
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Cites
Electrospinning and Electrospun Nanofibers: Methods, Materials, and Applications
Xue, J., Wu, T., Dai, Y., & Xia, Y. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00593 · Cited by 5,015
How a century of ammonia synthesis changed the world
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Defect engineering in photocatalytic materials
Bai, S., Zhang, N., Gao, C., & Xiong, Y. (2018) · Nano Energy · doi:10.1016/j.nanoen.2018.08.058 · Cited by 1,236
Self-citationDopant-induced electron localization drives CO2 reduction to C2 hydrocarbons
Zhou, Y., Che, F., Liu, M., Zou, C., Liang, Z., De Luna, P., Yuan, H., Li, J., Wang, Z., Xie, H., et al. (2018) · Nature Chemistry · doi:10.1038/s41557-018-0092-x · Cited by 1,171
Coupling N2 and CO2 in H2O to synthesize urea under ambient conditions
Chen, C., Zhu, X., Wen, X., Zhou, Y., Zhou, L., Li, H., Tao, L., Li, Q., Du, S., Liu, T., et al. (2020) · Nature Chemistry · doi:10.1038/s41557-020-0481-9 · Cited by 1,087
Self-citationZhao, Y., Zhao, Y., Shi, R., Wang, B., Waterhouse, G. I. N., Wu, L., Tung, C., & Zhang, T. (2019) · Advanced Materials · doi:10.1002/adma.201806482 · Cited by 1,015
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Self-citationIndustrial Upscaling of Electrospinning and Applications of Polymer Nanofibers: A Review
Persano, L., Camposeo, A., Tekmen, C., & Pisignano, D. (2013) · Macromolecular Materials and Engineering · doi:10.1002/mame.201200290 · Cited by 965
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Gu, K., Wang, D., Xie, C., Wang, T., Huang, G., Liu, Y., Zou, Y., Tao, L., & Wang, S. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202107390 · Cited by 432
Role of oxygen vacancy in metal oxides for photocatalytic CO2 reduction
Jiang, W., Loh, H., Low, B. Q. L., Zhu, H., Low, J., Heng, J. Z. X., Tang, K. Y., Li, Z., Loh, X. J., Ye, E., et al. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.122079 · Cited by 401
Self-citationZu, D., Ying, Y., Wei, Q., Xiong, P., Ahmed, M. S., Lin, Z., Li, M. M., Li, M., Xu, Z., Chen, G., et al. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202405756 · Cited by 291
Metadata
- Authors
- Bo, Y., Wang, H., Lin, Y., Yang, T., Ye, R., Li, Y., Hu, C., Du, P., Hu, Y., Liu, Z., Long, R., Gao, C., Ye, B., Song, L., Wu, X., & Xiong, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2021-06-14
- Volume
- 60
- Issue
- 29
- Pages
- 16085-16092
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3157483469
- Cited by
- 355
- References
- 31
- FWCI
- 9.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bo, Y., Wang, H., Lin, Y., Yang, T., Ye, R., Li, Y., Hu, C., Du, P., Hu, Y., Liu, Z., Long, R., Gao, C., Ye, B., Song, L., Wu, X., & Xiong, Y. (2021). Altering Hydrogenation Pathways in Photocatalytic Nitrogen Fixation by Tuning Local Electronic Structure of Oxygen Vacancy with Dopant. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202104001
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