The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Highly Reversible Aqueous Zinc Batteries enabled by Zincophilic–Zincophobic Interfacial Layers and Interrupted Hydrogen‐Bond Electrolytes
Open accessAbstract
Aqueous Zn batteries promise high energy density but suffer from Zn dendritic growth and poor low‐temperature performance. Here, we overcome both challenges by using an eutectic 7.6 m ZnCl 2 aqueous electrolyte with 0.05 m SnCl 2 additive, which in situ forms a zincophilic/zincophobic Sn/Zn 5(OH)8 Cl 2⋅H 2 O bilayer interphase and enables low temperature operation. Zincophilic Sn decreases Zn plating/stripping overpotential and promotes uniform Zn plating, while zincophobic Zn 5(OH)8 Cl 2⋅H 2 O top‐layer suppresses Zn dendrite growth. The eutectic electrolyte has a high ionic conductivity of ≈0.8 mS cm−1 even at −70 °C due to the distortion of hydrogen bond network by solvated Zn 2+ and Cl−. The eutectic electrolyte enables Zn∥Ti half‐cell a high Coulombic efficiency (CE) of >99.7 % for 200 cycles and Zn∥Zn cell steady charge/discharge for 500 h with a low overpotential of 8 mV at 3 mA cm−2. Practically, Zn∥VOPO 4 batteries maintain >95 % capacity with a CE of >99.9 % for 200 cycles at −50 °C, and retain ≈30 % capacity at −70 °C of that at 20 °C.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Computer Simulation of Liquids
Allen, M. P., & Tildesley, D. J. (2017) · doi:10.1093/oso/9780198803195.001.0001 · Cited by 20,945
Cited by
Huang, S., Hou, L., Li, T., Jiao, Y., & Wu, P. (2022) · Advanced Materials · doi:10.1002/adma.202110140 · Cited by 595
Insight on Organic Molecules in Aqueous Zn‐Ion Batteries with an Emphasis on the Zn Anode Regulation
Wang, D., Li, Q., Zhao, Y., Hong, H., Li, H., Huang, Z., Liang, G., Yang, Q., & Zhi, C. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202102707 · Cited by 478
A Double-Functional Additive Containing Nucleophilic Groups for High-Performance Zn-Ion Batteries
Wan, J., Wang, R., Liu, Z., Zhang, L., Liang, F., Zhou, T., Zhang, S., Zhang, L., Lu, Q., Zhang, C., et al. (2023) · ACS Nano · doi:10.1021/acsnano.2c11357 · Cited by 406
Metadata
- Authors
- Cao, L., Li, D., Soto, F. A., Ponce, V., Zhang, B., Ma, L., Deng, T., Seminario, J. M., Hu, E., Yang, X., Balbuena, P. B., & Wang, C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2021-07-16
- Volume
- 60
- Issue
- 34
- Pages
- 18845-18851
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3177199607
- Cited by
- 287
- References
- 1
- FWCI
- 14.69
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Highly Reversible Aqueous Zinc Batteries enabled by Zincophilic–Zincophobic Interfacial Layers and Interrupted Hydrogen‐Bond Electrolytes. https://app.cochat.ai/papers/10.1002/anie.202107378
- The paper
- Cao, L., Li, D., Soto, F. A., Ponce, V., Zhang, B., Ma, L., Deng, T., Seminario, J. M., Hu, E., Yang, X., Balbuena, P. B., & Wang, C. (2021). Highly Reversible Aqueous Zinc Batteries enabled by Zincophilic–Zincophobic Interfacial Layers and Interrupted Hydrogen‐Bond Electrolytes. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202107378
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
